RSS 1.0Chemical Sciences-Research Publications
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Metal- And Solvent-Free Multicomponent Decarboxylative A3-Coupling for the Synthesis of Propargylamines: Experimental, Computational, and Biological Investigations
(American Chemical Society, 2020)Decarboxylative A3-coupling of ortho-hydroxybenzaldehydes, secondary amines, and alkynoic acids is performed under catalyst and solvent-free conditions. The developed methodology provided a waste-free method for the synthesis ... -
Amido-amine derivative of alginic acid (AmAA) for enhanced adsorption of Pb(II) from aqueous solution
(Elsevier B.V., 2020)The present work reports the alternate synthesis of amido-amine derivative of alginic acid (AmAA) with high degree of functionalization. The AmAA have been characterized for percentage functionalization, functional group ... -
Comparative analysis of metabolites in contrasting chickpea cultivars
(Springer, 2019)Chickpea (Cicer arietinum L.) is a good source of nutrients for animals and human consumption. In the present study, we analyzed the anthocyanin and total phenolic contents in two contrasting (desi and kabuli) chickpea ... -
Recent advances in decarboxylative C-C bond formation using direct or in situ generated alkenyl acids
(Taylor and Francis Inc., 2019)In recent years, the reactions of abundantly available, inexpensive, and structurally diverse alkenyl acids (-C=C-COOH) with C-X (X�=�halogen) or C-H coupling partner have emerged as vital strategies for the streamlined ... -
Effect of 1-allyl-3-methylimidazoleum bromide on the motional dynamics and thermal stability of horse ferrocytochrome c
(American Institute of Physics Inc., 2019)The novel green solvent, ionic liquids emerged as potential solvents in executing the various in-vitro protein based applications. In the present study, we investigated the role of 1-allyl-3-methylimidazolium bromide ... -
Evaluation of heavy metals toxicity in the groundwater of some villages of Sirsa district of Haryana, India
(Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma, 2019)An attempt was made to assess the groundwater quality in some rural parts of Sirsa district of Haryana, India with respect to heavy metals contamination. For this purpose, 23 groundwater samples were collected from the ... -
Seed free high yield gold nanorods synthesis from single precursor gold(I) dithiophosphate complex
(John Wiley and Sons Ltd, 2019)In this work, we demonstrate a simple, one pot and seed free synthetic route for the formation of gold nanorods (Au NRs) via thermal decomposition of gold(I) dithiophosphate {[Au2{S2P(OiPr)2}2]n,} 1 complex as a molecular ... -
Copper hydride clusters in energy storage and conversion
(Royal Society of Chemistry, 2019)Hydrogen is seen as an increasingly important clean and sustainable energy source going into the future. There are a host of materials being investigated for the storage of hydrogen. In this frontier, we provide an overview ... -
Structural, kinetic and thermodynamic characterizations of SDS-induced molten globule state of a highly negatively charged cytochrome c
(Oxford University Press, 2019)This study presents the structural, kinetic and thermodynamic characterizations of previously unknown submicellar concentrations of SDS-induced molten globule (MGSDS) state of a highly negatively charged basedenatured ... -
Au/CdSe hybrid nanoflowers: a high photocurrent generating photoelectrochemical cells
(Springer, 2019)Photoelectrochemical cell composed of solution-processed nanoflower heterostructure of Au core and eight CdSe petals was investigated for enhanced photocurrent generation. The electrode of CdSe nanorods displayed photocurrent ... -
Zn(II) Di-isobutyldithiocarbamate Complex Enabled Efficient Synthesis of Au/ZnS Nanocomposite Core-shell in One Pot
(Wiley, 2019)Here, we demonstrate a one pot synthesis of gold/zinc sulphide (Au/ZnS) core-shell type composite nanostructure via thermal decomposition of single molecular precursor Zn(II)di-isobutyldithiocarbamate complex. In these ... -
Noble copper-silver-gold trimetallic nanobowls: An efficient catalyst
(Academic Press, 2019)We demonstrated the design of tiny bowls of copper-silver-gold (Cu-Ag-Au) alloy type noble trimetallic nanocrystals with a unique shape. All the structural characterizations confirm the presence of copper (Cu), silver (Ag), ... -
Nonlinear Optical Switching and Enhanced Nonlinear Optical Response of Au�CdSe Heteronanostructures
(ACS Publications, 2014)The metal�semiconductor heterostructures have recently emerged as a new class of functional materials for their potential applications due to plasmon-exciton interactions. Here, we demonstrate the nonlinear optical switching ... -
Factors Defining the Effects of macromolecularcrowding on dynamics and thermodynamics stability of heme proteins in-vitro
(Elsevier, 2018)The role of crowding agents on structure and activities of heme proteins has been established. Analysis of kinetic and thermodynamic parameters measured for CO-dissociation reaction of natively-folded carbonmonoxycytochrome ... -
Macromolecular crowding on Dynamics and Thermodynamic Stability of Heme Proteins
(Elsevier, 2018)Structural and molecular properties extracted from circular dichroism (CD), tryptophanfluorescence and 1-anilino-8-napthalene sulfonate (ANS) binding experiments suggest that the high concentration of synthetic crowding ... -
Single-molecule force-unfolding of titin I27 reveals a correlation between the size of the surrounding anions and its mechanical stability
(Royal Societty of chemistry, 2018)Each cellular protein is surrounded by a biochemical milieu that affects its stability and the associated function. The role of this surrounding milieu in the proteins’ mechanical stability remains largely unexplored. ... -
Factors defining the effects of macromolecular crowding on dynamics and thermodynamic stability of heme proteins in-vitro,
(Elsevier, 2018)The role of crowding agents on structure and activities of heme proteins has been established. Analysis of kinetic and thermodynamic parameters measured for CO-dissociation reaction of natively-folded carbonmonoxycytochrome ... -
Use of agricultural solid wastes as adsorbent
(Material Research Forum LLC, 2018) -
In situ reductive regeneration of zerovalent iron nanoparticles immobilized on cellulose for atom efficient Cr(vi) adsorption
(Royal Society of Chemistry, 2015)Zerovalent iron nanoparticles (nZVI) (11.8 � 0.2% w/w) immobilized on microcrystalline cellulose (C-nZVI) were synthesized and studied for Cr(vi) sorption. The material showed good atom economy for Cr(vi) adsorption (562.8 ... -
Genetic engineering of poplar: Current achievements and future goals
(Springer Singapore, 2017)Global biomass demand for industrial applications is ever increasing especially in biofuels and pulp industries. Poplar is likely to have great biological advantages over the other forest trees which include small genome ...
