Browsing by Author "Akram, Md. Khursheed"

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    Green Synthesis of TiO2 Nanoparticles Using Acorus calamus Leaf Extract and Evaluating its Photocatalytic and In Vitro Antimicrobial Activity
    (MDPI, 2022-01-31T00:00:00) Ansari, Afzal; Siddiqui, Vasi Uddin; Rehman, Wahid Ul; Akram, Md. Khursheed; Siddiqi, Weqar Ahmad; Alosaimi, Abeer M.; Hussein, Mahmoud A.; Rafatullah, Mohd
    Here, we present an innovative and creative sustainable technique for the fabrication of titania (TiO2) using Acorus calamus (A. calamus) leaf extract as a new biogenic source, as well as a capping and reducing agent. The optical, structural, morphological, surface, and thermal character-istics of biosynthesized nanoparticles were investigated using UV, FTIR, SEM, DLS, BET, and TGA-DSC analysis. The phase formation and presence of nanocrystalline TiO2 were revealed by the XRD pattern. FTIR analysis revealed conjugation, as well as the presence of Ti�O and O�H vibrational bands. The nanoparticles were noticed to be globular, with an average size of 15�40 nm, according to the morphological analysis, and the impact of size quantification was also investigated using DLS. The photocatalytic activity of bare, commercial P-25 and biosynthesized TiO2 (G-TiO2) nano-particles in aqueous solution of rhodamine B (RhB) dye was investigated under visible light irradiation at different time intervals. The biosynthesized TiO2 nanoparticles exhibited strong photocata-lytic activity, degrading 96.59% of the RhB dye. Different kinetic representations were utilized to analyze equilibrium details. The pseudo-first-order reaction was best suited with equilibrium rate constant (K1) and regression coefficients (R2) values 3.72 � 10?4 and 0.99, respectively. The antimi-crobial efficacy of the prepared nanoparticles was investigated using the disc diffusion technique. Further, biosynthesized TiO2 showed excellent antimicrobial activity against the selected gram-pos-itive staining (B. subtilis, S. aureus) over gram-negative (P. aeruginosa, E. coli) pathogenic bacteria in comparison to bare TiO2. � 2022 by the authors. Licensee MDPI, Basel, Switzerland.
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    Green Synthesis of TiO2 Nanoparticles Using Acorus calamus Leaf Extract and Evaluating its Photocatalytic and In Vitro Antimicrobial Activity
    (MDPI, 2022-01-31T00:00:00) Ansari, Afzal; Siddiqui, Vasi Uddin; Rehman, Wahid Ul; Akram, Md. Khursheed; Siddiqi, Weqar Ahmad; Alosaimi, Abeer M.; Hussein, Mahmoud A.; Rafatullah, Mohd
    Here, we present an innovative and creative sustainable technique for the fabrication of titania (TiO2) using Acorus calamus (A. calamus) leaf extract as a new biogenic source, as well as a capping and reducing agent. The optical, structural, morphological, surface, and thermal character-istics of biosynthesized nanoparticles were investigated using UV, FTIR, SEM, DLS, BET, and TGA-DSC analysis. The phase formation and presence of nanocrystalline TiO2 were revealed by the XRD pattern. FTIR analysis revealed conjugation, as well as the presence of Ti�O and O�H vibrational bands. The nanoparticles were noticed to be globular, with an average size of 15�40 nm, according to the morphological analysis, and the impact of size quantification was also investigated using DLS. The photocatalytic activity of bare, commercial P-25 and biosynthesized TiO2 (G-TiO2) nano-particles in aqueous solution of rhodamine B (RhB) dye was investigated under visible light irradiation at different time intervals. The biosynthesized TiO2 nanoparticles exhibited strong photocata-lytic activity, degrading 96.59% of the RhB dye. Different kinetic representations were utilized to analyze equilibrium details. The pseudo-first-order reaction was best suited with equilibrium rate constant (K1) and regression coefficients (R2) values 3.72 � 10?4 and 0.99, respectively. The antimi-crobial efficacy of the prepared nanoparticles was investigated using the disc diffusion technique. Further, biosynthesized TiO2 showed excellent antimicrobial activity against the selected gram-pos-itive staining (B. subtilis, S. aureus) over gram-negative (P. aeruginosa, E. coli) pathogenic bacteria in comparison to bare TiO2. � 2022 by the authors. Licensee MDPI, Basel, Switzerland.