Browsing by Author "Banu, J. Rajesh"

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    Electrode modification and its application in microbial electrolysis cell
    (Elsevier, 2022-02-04T00:00:00) Rani, Gini; Banu, J. Rajesh; Yogalakshmi, K.N.
    The microbial electrolysis cell (MEC) is a sustainable technology that degrades organic substrate to produce hydrogen, an important energy carrier. However, its large-scale practical application is hampered because of several factors including electrodes material, reactor designs, substrates, and high-cost catalysts. Electrodes in particular are fundamental components which determine redox reaction and transport of electric charge. The surface of the electrode is where the equilibrium of redox reaction is established between the electrode surface and the electrolyte (substrate). Therefore, modification of electrodes is emphasized much recently. Modified electrodes have wide application as electrochemical devices, chemical analysis, biosensors, and many more. The electrode modification is carried out to bring improved properties in the electrode by altering its morphology or molecular structure. Apart from high conductivity and low resistance, the modified electrodes develop increased sensitivity, selectivity, corrosion resistance, electrochemical, and chemical stability. They also possess large potential window. Moreover, electrode modification using nanomaterials and conductive polymers favors electrocatalysis process. Studies related to MEC using modified electrodes have reported improved wastewater treatment and hydrogen production along with enhanced energy recovery. In the present chapter, the mechanics of electrode in an electrochemical system, in general, is explained in detail. Moreover, the overview of different techniques for the modification of the electrodes and their applications in MEC has been expensively entailed. � 2022 Elsevier Inc.
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    Impact of light on microalgal photosynthetic microbial fuel cells and removal of pollutants by nanoadsorbent biopolymers: Updates, challenges and innovations
    (Elsevier Ltd, 2021-10-20T00:00:00) Khan, Mohd Jahir; Singh, Nikhil; Mishra, Sudhanshu; Ahirwar, Ankesh; Bast, Felix; Varjani, Sunita; Schoefs, Benoit; Marchand, Justine; Rajendran, Karthik; Banu, J. Rajesh; Saratale, Ganesh Dattatraya; Saratale, Rijuta Ganesh; Vinayak, Vandana
    Photosynthetic microbial fuel cells (PMFCs) with microalgae have huge potential for treating wastewater while simultaneously converting light energy into electrical energy. The efficiency of such cells directly depends on algal growth, which depends on light intensity. Higher light intensity results in increased potential as well as enhancement in generation of biomass rich in biopolymers. Such biopolymers are produced either by microbes at anode and algae at cathode or vice versa. The biopolymers recovered from these biological sources can be added in wastewater alone or in combination with nanomaterials to act as nanoadsorbents. These nanoadsorbents further increase the efficiency of PMFC by removing the pollutants like metals and dyes. In this review firstly the effect of different light intensities on the growth of microalgae, importance of diatoms in a PMFC and their impact on PMFCs efficiencies have been narrated. Secondly recovery of biopolymers from different biological sources and their role in removal of metals, dyes along with their impact on circular bioeconomy have been discussed. Thereafter bottlenecks and future perspectives in this field of research have been narrated. � 2021 Elsevier Ltd
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    Impact of light on microalgal photosynthetic microbial fuel cells and removal of pollutants by nanoadsorbent biopolymers: Updates, challenges and innovations
    (Elsevier Ltd, 2021-10-20T00:00:00) Khan, Mohd Jahir; Singh, Nikhil; Mishra, Sudhanshu; Ahirwar, Ankesh; Bast, Felix; Varjani, Sunita; Schoefs, Benoit; Marchand, Justine; Rajendran, Karthik; Banu, J. Rajesh; Saratale, Ganesh Dattatraya; Saratale, Rijuta Ganesh; Vinayak, Vandana
    Photosynthetic microbial fuel cells (PMFCs) with microalgae have huge potential for treating wastewater while simultaneously converting light energy into electrical energy. The efficiency of such cells directly depends on algal growth, which depends on light intensity. Higher light intensity results in increased potential as well as enhancement in generation of biomass rich in biopolymers. Such biopolymers are produced either by microbes at anode and algae at cathode or vice versa. The biopolymers recovered from these biological sources can be added in wastewater alone or in combination with nanomaterials to act as nanoadsorbents. These nanoadsorbents further increase the efficiency of PMFC by removing the pollutants like metals and dyes. In this review firstly the effect of different light intensities on the growth of microalgae, importance of diatoms in a PMFC and their impact on PMFCs efficiencies have been narrated. Secondly recovery of biopolymers from different biological sources and their role in removal of metals, dyes along with their impact on circular bioeconomy have been discussed. Thereafter bottlenecks and future perspectives in this field of research have been narrated. � 2021 Elsevier Ltd
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    Statistical optimization of operating parameters of microbial electrolysis cell treating dairy industry wastewater using quadratic model to enhance energy generation
    (Elsevier Ltd, 2022-04-28T00:00:00) Rani, Gini; Banu, J. Rajesh; Kumar, Gopalakrishnan; Yogalakshmi, K.N.
    The performance of Microbial electrolysis cell (MEC) is affected by several operating conditions. Therefore, in the present study, an optimization study was done to determine the working efficiency of MEC in terms of COD (chemical oxygen demand) removal, hydrogen and current generation. Optimization was carried out using a quadratic mathematical model of response surface methodology (RSM). Thirteen sets of experimental runs were performed to optimize the applied voltage and hydraulic retention time (HRT) of single chambered batch fed MEC operated with dairy industry wastewater. The operating conditions (i.e) an applied voltage of 0.8 V and HRT of 2 days that showed a maximum COD removal response was chosen for further studies. The MEC operated at optimized condition (HRT- 2 days and applied voltage- 0.8 V) showed a COD removal efficiency of 95 � 2%, hydrogen generation of 32 � 5 mL/L/d, Power density of 152 mW/cm2 and current generation of 19 mA. The results of the study implied that RSM, with its high degree of accuracy can be a reliable tool for optimizing the process of wastewater treatment. Also, dairy industry wastewater can be considered to be a potential source to generate hydrogen and energy through MEC at short HRT. � 2022 Hydrogen Energy Publications LLC