Browsing by Author "Kumar, Avneesh"
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Item Critical review on uranium and arsenic content and their chemical mobilization in groundwater: A case study of the Malwa region Punjab, India(Elsevier B.V., 2023-05-03T00:00:00) Kumar, Vajinder; Maity, Arnab; Kumar, Avneesh; Saha, Sandip; Kay, Paul; Singh, Baljinder; Mukherjee, TirthaThe presence of pollutants like uranium and arsenic in the groundwater can have a terrible impact on people's health (both radiologically and toxicologically) and their economic conditions. Their infiltration into groundwater can occur through geochemical reactions, natural mineral deposits, mining and ore processing. Governments and scientists are working to address these issues, and significant progress has been achieved, but it's challenging to deal with and mitigate without adequately understanding the different chemical processes and the mobilization mechanism of these hazardous chemicals. Most of the articles and reviews have focused on the particular form of contaminants and specific sources of pollution, such as fertilizers. However, no literature report exists explaining why particular forms appear and the possible basis of their chemical origins. Hence, in this review, we tried to answer the various questions by devising a hypothetical model and chemical schematic flowcharts for the chemical mobilization of arsenic and uranium in groundwater. An effort has been made to explain how chemical seepage and excessive groundwater use resulted in the change in aquifers' chemistry, as evidenced by their physicochemical parameters and heavy metal analysis. Many technological advancements have taken place to mitigate these issues. Still, in low-middle-income countries, especially in the Malwa region of Punjab, also known as Punjab's cancer belt, paying a high amount for installing and maintaining these technologies is an unviable option. In addition to working to improve people's access to sanitary facilities and clean water to drink, the policy-level intervention would focus on increasing community awareness and continued research on developing better and more economical technologies. Our designed model/chemical flowcharts will help policymakers and researchers better understand the problems and alleviate their effects. Moreover, these models can be utilized in other parts of the globe where similar questions exist. This article emphasises the value of understanding the intricate issue of groundwater management through a multidisciplinary and interdepartmental approach. � 2023 Elsevier B.V.Item Exogenous application of biostimulants for As stress tolerance in crop plants(Elsevier, 2023-08-04T00:00:00) Garg, Tashima; Arora, Bhumika; Bokolia, Muskan; Joshi, Anjali; Kumar, Vinay; Kumar, Avneesh; Kaur, SimranjeetArsenic (As) is a nonessential toxic metalloid existing in two different inorganic forms: arsenite As (III) and arsenate As (V) which cause hindrance in plant developmental processes and are hazardous to human beings. As contamination is a major environmental issue as it stimulates physiological and metabolic dysfunctions, for instance, nutrient and redox imbalance, rate of photosynthesis, and membrane integrity, ultimately leading to reduced crop yield. Plants show detoxification processes to overcome As toxic effects by effluxing excess metal ions through metal transporters, accumulating As in the vacuole, and producing antioxidant enzymes. In recent times, the exogenous application of various biostimulants such as hormones, antioxidants, osmolytes, and others is being explored to combat As-mediating injuries to crop plants. These compounds are effective in improving seed germination, antioxidant enzyme activity, plant biomass, and overall growth of the plants. The objective of this chapter is to provide recent knowledge on the biostimulants hallmarks to alleviate As stress in crop plants. � 2023 Elsevier Inc. All rights reserved.Item Exogenous application of biostimulants for As stress tolerance in crop plants(Elsevier, 2023-08-04T00:00:00) Garg, Tashima; Arora, Bhumika; Bokolia, Muskan; Joshi, Anjali; Kumar, Vinay; Kumar, Avneesh; Kaur, SimranjeetArsenic (As) is a nonessential toxic metalloid existing in two different inorganic forms: arsenite As (III) and arsenate As (V) which cause hindrance in plant developmental processes and are hazardous to human beings. As contamination is a major environmental issue as it stimulates physiological and metabolic dysfunctions, for instance, nutrient and redox imbalance, rate of photosynthesis, and membrane integrity, ultimately leading to reduced crop yield. Plants show detoxification processes to overcome As toxic effects by effluxing excess metal ions through metal transporters, accumulating As in the vacuole, and producing antioxidant enzymes. In recent times, the exogenous application of various biostimulants such as hormones, antioxidants, osmolytes, and others is being explored to combat As-mediating injuries to crop plants. These compounds are effective in improving seed germination, antioxidant enzyme activity, plant biomass, and overall growth of the plants. The objective of this chapter is to provide recent knowledge on the biostimulants hallmarks to alleviate As stress in crop plants. � 2023 Elsevier Inc. All rights reserved.Item Genome-wide identification of NAC transcription factors in Avena sativa under salinity stress(Elsevier B.V., 2023-10-29T00:00:00) Bokolia, Muskan; Singh, Baljinder; Kumar, Avneesh; Goyal, Nandni; Singh, Kashmir; Chhabra, RavindreshBackground: NAC (NAM, ATAF1/2, and CUC2) is one of the most prominent family of plant-specific transcription factors that play diverse roles in plant growth and development as well as in abiotic stress responses in plants. The members of this family are recognized by presence of typical conserved NAC domain at the N-terminal and diverse C-terminal region. Results: In this study, we have identified 101 Avena sativa NAC (AsNAC) genes from the available Avena genome database. Genes were analyzed for their physicochemical properties, conserved motifs, gene structure, chromosomal localization, phylogenetic relationship, and cis-acting elements. The phylogenetic analysis illustrated that there were 15 subgroups in both Avena sativa and Arabidopsis thaliana. Mainly four types of cis-acting regulatory elements were present in the promoter regions of NAC genes, including hormone-responsive, light-responsive, stress-responsive and growth and developmental responsive elements. The chromosomal mapping analysis concluded that 101 NAC genes of Avena sativa were unevenly distributed on 21 chromosomes. Expression analysis identified 27 Avena NAC genes that respond to salt stress based on transcriptomic data analysis available on the NCBI SRA database. Significance: The genome-wide identification and molecular analysis of NAC TFs involved in environmental stress responses have the ability to overcome the limitations that came across in producing the transgenic crops with superior quality and improved production under abiotic stressed conditions. Future prospectives: These NAC genes may be considered as potential candidates for further explorations of functional analysis and could be used to develop stress tolerant lines in Avena sativa. � 2023 The Author(s)Item Synergistic effect of pistachio shell powder and nano-zerovalent copper for chromium remediation from aqueous solution(Springer Science and Business Media Deutschland GmbH, 2021-07-06T00:00:00) Kumar, Sandeep; Brar, Ravinderdeep Singh; Babu, J. Nagendra; Dahiya, Amarjeet; Saha, Sandip; Kumar, AvneeshPistachio shell powder supported nano-zerovalent copper (ZVC@PS) material prepared by borohydride reduction was characterized using SEM, FTIR, XRD, TGA/DTA, BET, and XPS. SEM, XRD, and XPS revealed the nano-zerovalent copper to consist of a core-shell structure with CuO shell and Cu(0) core with a particle size of 40�100 nm and spherical morphology aggregated on PS biomass. ZVC@PS was found to contain 39% (w/w %) Cu onto the pistachio shell biomass. Batch sorption of Cr(VI) from the aqueous using ZVC@PS was studied and was optimized for dose (0.1�0.5 g/L), initial Cr(VI) concentration(1�20 mg/L), and pH (2�12). Optimized conditions were 0.1 g/L doses of sorbent and pH=3 for Cr(VI) adsorption. Langmuir and Freundlich adsorption isotherm models fitted well to the adsorption behavior of ZVC@PS for Cr(VI) with a pseudo-second-order kinetic behavior. ZVC@PS (0.1g/L) exhibits qmax for Cr(VI) removal up to 110.9 mg/g. XPS and other spectroscopic evidence suggest the adsorption of Cr(VI) by pistachio shell powder, coupled with reductive conversion of Cr(VI) to Cr(III) by ZVC particles to produce a synergistic effect for the efficient remediation of Cr(VI) from aqueous medium. Graphical abstract: [Figure not available: see fulltext.] � 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.