Browsing by Author "Sahare, P.D."

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    Enhanced capacitive behaviour of graphene nanoplatelets embedded epoxy nanocomposite
    (Springer, 2021-01-06T00:00:00) Raval, Bhargav; Sahare, P.D.; Mahapatra, S.K.; Banerjee, I.
    For the development of advanced polymer nanocomposite processability, high-quality and cost-efficiency plays a crucial role which combines mechanical robustness with functional electrochemical properties. In this study, we fabricated the epoxy/graphene nanocomposite (EGNC) with different wt% ratio of graphene nanoplatelets (GNPs). The EGNCs were fabricated through a solution mixing process and used it as an electrode to enhance electrochemical properties. The GNPs and EGNCs characterized using XRD, Raman spectroscopy, ATR FT-IR, and FE-SEM for the structural conformation and surface morphological study. The electrochemical analysis results show significant improvement in the specific capacitance in the EGNC samples as compared to the blank epoxy film. Specific capacitance 17.74 Fg?1 was recorded at 10 mVs?1 scan rate in 1.0�M KOH electrolyte solution for the 1.0 wt% EGNC film by cyclic voltammetry analysis. The Galvanostatic charge�discharge and Ragone plots also show mended results by the addition of GNPs. � 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature.
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    Spectroscopic analysis of Muga silk nanoparticles synthesized by microwave method
    (Blackwell Publishing Ltd, 2020-04-26T00:00:00) Asapur, Prithvi; Banerjee, Indrani; Sahare, P.D.; Mahapatra, Santosh
    Muga silk nanoparticles (MSNP) were synthesized using a microwave-assisted radiolysis method. The effect of microwave on the Muga protein secondary structures was analyzed. The evolution of the secondary structure from random coils to the ?-sheets was determined by using FTIR, circular dichroism and X-ray diffraction techniques. The results showed that Muga silk fibroin protein contained the primary structure in silk-I state. When the protein was irradiated with microwave, nanoparticle synthesis was possible having silk-II state imparting crystallinity. The silk nanoparticles were characterized by a particle size analyzer and found to be of ~240�nm in size. The optical properties of these nanoparticles were studied by UV�vis. spectroscopy and photoluminescence. For studying thermal properties, differential scanning calorimetry was performed that revealed early glass transition, which could be attributed to the presence of water and proteins. It also revealed that nanoparticles are thermally stable. Such studies are important for understanding more about the MSNP and would be beneficial for their further wide applications. � 2020 International Union of Biochemistry and Molecular Biology, Inc.