Browsing by Author "Sahoo P.K."

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    Geochemical relationship and translocation mechanism of arsenic in rice plants: A case study from health prone south west Punjab, India
    (Elsevier B.V., 2020) Sharma S.; Kumar R.; Sahoo P.K.; Mittal S.
    Rice is a recognised hyperaccumulator of arsenic (As) and is a serious concern for rice varieties grown in As contaminated soil-water systems. In this regard, groundwater, soil and rice-plant samples (two varieties: PR122 and PUSA1121) collected from 10 sites of district Bathinda were studied for their physicochemical characteristics and As concentration. In vitro studies were carried out to study the role of antioxidant enzymes in As uptake and translocation mechanism. The results showed that the As concentration in water and soil samples ranged from 54 to 132 ?g/L and 6.62–19.56 mg/kg, respectively. The As in rice roots, straw, husk and grains of PR122 ranged from 1.89 to 8.56, 0.20–5.3, 0.12–1.42, 0–0.12 mg/kg, respectively and 1.24–8.16, 0.54–5.11, 0.11–1.06 mg/kg and below detection limit (BDL), respectively for PUSA1121. Although a moderate correlation (r = 0.37) was observed between As in groundwater and soil, the higher As concentration found in both media in Behman and Teona areas indicates that we cannot ignore the role of groundwater in As contamination. Spearman correlation analysis indicates the positive impact of As from groundwater and soil in aerial parts of both rice varieties except grains. In vitro studies showed an increase in antioxidant enzyme activities with the increase in As toxicity (15–60 ?M), which indicates As tolerant behaviour in both rice varieties. The hazard quotient (HQ) for both rice varieties is < 1, which suggest no potential non-cancer health risk, however the cancer risk (CR) for PR122 variety exceeded (2.06 – 10?4) the acceptable limit of 1 × 10?4 (USEPA). Based on the present study, it can be concluded that both the rice varieties are tolerant to As and their grains are safe for human consumption.
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    Ground/drinking water contaminants and cancer incidence: A case study of rural areas of South West Punjab, India
    (Taylor and Francis Inc., 2019) Kaur G.; Kumar R.; Mittal S.; Sahoo P.K.; Vaid U.
    This study was carried out in the rural areas of South West Punjab, India, to evaluate the groundwater quality and cancer incidence. The epidemiological study was carried using standardized questionnaire method, and the groundwater samples were analyzed for heavy metals by ICP-MS and AAS. The results showed that the cancer prevalence was highest in the age group of > 60, followed by >45–60 years old in both males and females. The average cancer rate in females (272 cases/lakh) was ?3 times higher than the India's national cancer average of 80 cases/lakh. The mean concentration of As(27.59 µg/L), Pb (48.3 µg/L), U (96.56 µg/L), NO3– (67.32 mg/L), and F– (4.7 mg/L) exceeded the drinking water limits of WHO/BIS. Health risk analysis indicated that As, Pb, U, and F– with NO3– are the major groundwater contaminants, which may be one of the potential cause of cancer incidences. Multivariate analyses reveal that anthropogenic activities are source of NO3–, whereas U, As, and F– are mainly of geogenic origin. The carcinogenic and non-carcinogenic risk followed in the order of As > Pb and U > F–>NO3–>Cu > Zn, respectively. Further, correlations between cancer incidence and groundwater quality have been discussed.
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    High resolution hydrogeochemical survey and estimation of baseline concentrations of trace elements in surface water of the Itacaiúnas River Basin, southeastern Amazonia: Implication for environmental studies
    (Elsevier B.V., 2019) Sahoo P.K.; Dall'Agnol R.; Salomão Gabriel Negreiros; da Silva Ferreira Junior J.; Silva M.S.; e Souza Filho P.W.M.; Powell M.A.; Angélica. Rômulo Simões; Pontes P.R.; da Costa M.F.; Siqueira J.O.
    A high resolution systematic geochemical mapping at regional-scale is considered to be the best available method to estimate geochemical baseline levels of trace elements in stream water, and is an essential part of environmental risk assessment. This methodology was applied in a project in the Itacaiúnas River Basin, southeastern Amazon, Brazil, which includes several mines of the Carajás Mineral Province (as part of the Itacaiúnas Geochemical Mapping and Background Project, ItacGMBP). A total of 1429 samples (including 55 duplicates) were collected in 2017 at 900 sites at one sample per microbasin, during both dry and rainy periods. The analyses of 34 elements were carried out using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). In general, the waters are slightly alkaline and are classified as mixed Ca-Na-HCO3 type, indicating that they are mainly influenced by silicate rock weathering. Most metal concentrations in the water are low, except Fe and Mn. Seasonality explains differences in metal concentrations, with higher values being obtained in the rainy season. Baseline threshold values (BTVs) were calculated separately for both seasons by employing different statistical methods: iterative 2σ and DF preferentially delivered a more restrictive or conservative levels, which can be represenative of the natural BTVs (NBTVs), considering as the least degraded with low or no significant level of anthropogenic influence; and 98th percentile provides the ambient BTVs (ABTVs), which consists of natural plus diffuse anthropogenic input in the defined area. The ABTVs of Fe and Mn significantly exceed the WHO (1998) and CONAMA 357/05 limits. Spatial distribution indicates that Fe and Mn are not strictly related to geologic setting, rather they are highly influenced by specific local land use as well as deep weathering of the catchment and intense leaching and run-off during the rainy season. However, higher Mn occurrence in the dry period results from redox cycling of Fe and Mn via biogeochemical processes. The ABTVs of Ni, Cr, and V are controlled by bedrock lithology (geologic setting), mainly associated with mafic-ultramafic rocks; Cu is associated with two large hydrothermally mineralized copper belts. The estimation of baseline levels of As, Se, and Pb were highly limited due to of the large number of samples with results less than detection limits, in this case the 95th percentile was used for their BTVs. Geochemical data as well as anomalous values for most of the metals indicate that anthropogenic influence from point sources is highly negligible in the basin, except at a few points, where high NO3- has been observed, probably due to more intense human and livestock activity. This study demonstrates that site-specific geochemical baseline assessment is a crucial factor when evaluating surficial water conditions in a large basin.
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    Source apportionment, chemometric pattern recognition and health risk assessment of groundwater from southwestern Punjab, India
    (Springer, 2020) Kumar R.; Mittal S.; Sahoo P.K.; Sahoo S.K.
    The groundwater quality of southwestern Punjab, India, is a serious cause of concern due to the presence of chemical contaminants in it. However, limited studies of groundwater quality, sources of chemical contaminants and their health risks are available for the region. Hence, this study was conducted to investigate the source, distribution and potential health risk assessment of groundwater quality in three districts of southwestern Punjab, India. The spatial distribution of groundwater chemical contaminants and their potential health risks have been illustrated using inverse distance weighting interpolation technique. The concentration of fluoride (F?; ranged from 0.08 to 4.79 mg L−1) exceeded the WHO limit (1.5 µg L−1) in 80 and 50% samples collected from Bathinda and Ludhiana districts, respectively. The uranium (U) concentration ranged from 0.5 to 432 µg L−1 and shows ~ 85%, 75% and 10% of samples collected from Bathinda, Barnala and Ludhiana districts exceeded the WHO drinking water limit (30 µg L−1), respectively. The groundwater quality of the Bathinda district is a matter of concern due to elevated levels of alkalinity, hardness, fluoride, uranium and nitrate (NO3 ?). The principal component analysis shows close association between F? and U, which indicates their geogenic origin. Further, they also seem to be subordinately influenced by diffuse anthropogenic activities. The clustering of Cu and Pb with NO3 ? and SO4 2? indicates their anthropogenic origin. The non-carcinogenic health risk assessment indicates that F?, NO3 ? and U are the major health risk pollutants in the study area. The carcinogenic health risk of As and Cr exceeded the USEPA limits (10?6) in the entire study area, but observed to be more serious for the district Bathinda (10−3–10−5). The spatial distribution maps illustrate that the health risk for Bathinda district inhabitants is higher than Barnala and Ludhiana districts.