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Author: search.filters.author.Jacinto, CarlosSubject: search.filters.subject.p-BiOBr/n-ZnWO<sub>4</sub> heterostructures

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    BiOBr/ZnWO4 heterostructures: An important key player for enhanced photocatalytic degradation of rhodamine B dye and antibiotic ciprofloxacin
    (Elsevier Ltd, 2022-11-07T00:00:00) Santana, Rafael W.R.; Lima, A.E.B.; Souza, Luiz K.C. de; Santos, Evelyn C.S.; Santos, C.C.; Menezes, A.S. de; Sharma, Surender K.; Cavalcante, L.S.; Maia da Costa, Marcelo E.H.; Sales, T.O.; Jacinto, Carlos; Luz, G.E.; Almeida, M.A.P.
    We report a facile synthesis of p-BiOBr/n-ZnWO4 heterostructures by hydrothermal/precipitation method as an important key player to enhance the photocatalytic degradation of Rhodamine B (RhB) dye and ciprofloxacin antibiotic. The structural and microstructural features confirm that p-BiOBr/n-ZnWO4 heterostructures display a mixed tetragonal/monoclinic phase with the presence of several n-ZnWO4 nanocrystals on the surface of petals of flower-like p-BiOBr microcrystals. X-ray photoluminescence (XPS) analysis of BiOBr exhibits the existence of Bi, O, and Br, whereas BiOBr/ZnWO4-5%, in addition to Bi, O, and Br, consist of signature of Zn and W. UV�Visible spectra of p-BiOBr/n-ZnWO4-5% showed better absorption than p-BiOBr and n-ZnWO4, which displayed an enhanced collection of photons in the heterojunction. An intense photoluminescence emission at room temperature was observed for p-BiOBr microcrystals as compared to p-BiOBr/n-ZnWO4. We observed the best photocatalytic activity for p-BiOBr/n-ZnWO4-2.5% in the degradation of RhB dye at 99.4% in 25 min and CIP antibiotic at 58.2% in 170 min, which is assigned due to high surface area SBET (13 m2/g), pore size, providing active catalytic sites for bonding chemical and surface interaction and bonding chemical between the bromide/oxides. Finally, we have investigated the use of scavengers for isopropanol, benzoquinone, and sodium azide, which proves that the hydroxyl (�OH) and superoxide (O2?) radicals as the foremost reactive oxygen spicies (ROS) in photocatalytic degradation of RhB dye and antibiotic CIP. � 2022 Elsevier Ltd