Department Of Chemistry

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Subject: search.filters.subject.Hexavalent chromium

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    Reduced and oxidized rice straw biochar for hexavalent chromium adsorption: Revisiting the mechanism of adsorption
    (Elsevier Ltd, 2023-11-01T00:00:00) Dahiya, Amarjeet; Bhardwaj, Akanksha; Rani, Archana; Arora, Meenu; Babu, J. Nagendra
    Surface oxygen functional groups of biochar were tuned by oxidation and reduction of biochar for establishing Cr(VI) adsorption mechanism. Oxygen functional groups (OFGs) on the surface of leached rice straw biochar (LBC4-6) obtained from pyrolysis at 400, 500 and 600 �C, were oxidized to furnish OBC4-6 using modified Hummer's method. Reduced biochar RBC4-6 were obtained by esterification and NaBH4/I2 reduction of oxidized biochar (OBC4-6). The modified biochar were characterized by increase in O/C and H/C ratio, respectively, in case of OBC4-6 and RBC4-6. The Cr(VI) adsorption by modified biochar LBC4-6, OBC4-6, and RBC4-6 showed optimum conditions of pH 3 and dose 0.1 g/L with a good non-linear fit for Langmuir & Freundlich isotherm. The maximum adsorption (Qm) followed the trend: OBC4 (17.47 mg/g) > RBC4 (15.23) > OBC5 (13.23) > LBC4 (10.23) > RBC5 (9.83) > OBC6 (9.60) > RBC6 (7.24) > LBC5 (6.32) > LBC6 (5.98). The adsorption kinetics for adsorption of Cr(VI) on to modified biochar fits pseudo second order (PSO), Elovich and intraparticle diffusion kinetics, showing a chemisorptions in case of biochar L/O/RBC4-6. The lower temperature modified biochar O/RBC4 show better Cr(VI) adsorption. X-ray Photoelectron Spectroscopy (XPS) studies establish optimum OFGs for reduction of Cr(VI) and chelation of the reduced Cr(III). Adsorption and stripping cycles show the oxidized and reduced biochar as better adsorbents with excellent stripping of Cr up to >98 % upon desorption with 1 M NaOH. � 2023
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    Nickel oxide decorated zinc oxide composite nanorods: Excellent catalyst for photoreduction of hexavalent chromium
    (Academic Press Inc., 2018) Singh, Simranjeet; Ahmed,Imtiaz; Haldar, Krishna Kanta
    In light of the growing interest and ability to search for new materials, we have synthesized Nickel oxide (NiO) nanoparticles decorated Zinc (ZnO) nanorods composite (NiO/ZnO) nanostructure. The NiO/ZnO heterostructure formation was confirmed by X-ray powder diffraction and high-resolution transmission electron microscopy (HRTEM). The fabricated environmental friendly NiO/ZnO composite nanostructure shows a well-defined photoreduction characteristic of hexavalent Chromium (Cr) (VI) to tri-valent Chromium (Cr) (III) under UV-light. Such an enhanced photoreduction property is attributed due to the decreased electron-hole recombination process which was proved by photoluminescence (PL) spectroscopy, photocurrent study, and electrochemical impedance spectroscopy. Furthermore, the photocatalytic activity rate of the NiO decorated ZnO nanorods was much higher than that of bare ZnO nanorods for the reduction of chromium (VI) and the rate is found to be 0.306 min?1. These results have demonstrates that suitable surface engineering may open up new opportunities in the development of high-performance photocatalyst. ? 2018 Elsevier Inc.