Department Of Physics
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Item Synergistic improvement in electrochemical performance of Cr-doped MoS2/CuCo2S4 binary composite for hybrid supercapacitors(Elsevier Ltd, 2023-10-31T00:00:00) Kour, Pawanpreet; Kour, Simran; Deeksha; Sharma, A.L.; Yadav, KamleshThe synergistic effect of transition metal doping and composite formation can be imperative to improve the limited conductivity and inferior cyclic stability of MoS2 for supercapacitors. In this work, firstly, the impact of Cr-doping on the electrochemical activity of MoS2 has been discussed. Afterwards, the optimized Cr-doped MoS2 (CrMS-5) sample has been combined with CuCo2S4 (CCS) to further enhance its charge storage ability and cyclic stability. The CrMS-5/CCS composite delivers tremendous electrochemical activity as an electrode with a specific capacity of approximately 1324.08 C g?1 at 4 A g?1. The outstanding performance of the doped binary composite is on account of the synergism between doping and composite formation that results in increased conductivity and numerous redox active sites for charge storage. Furthermore, a symmetric supercapacitor device (SSC) has been fabricated using a CrMS-5/CCS electrode. It attains a high energy density of 46.63 Wh kg?1 corresponding to 1 kW kg?1 of power and exhibits remarkable cyclic stability of 81% for up to 5,000 cycles. The device illuminates a star-shaped LED panel of 12 red LEDs for 30 min. Thus, the above outcomes demonstrate the superiority of the doped MoS2-based composites for high-energy symmetric supercapacitors. � 2023 Elsevier LtdItem Theoretical investigation of quantum capacitance of Co-doped ?-MnO2 for supercapacitor applications using density functional theory(Royal Society of Chemistry, 2023-09-07T00:00:00) Vijayan, Ariya K.; Sreehari, M.S.; Kour, Simran; Dastider, Saptarshi Ghosh; Mondal, Krishnakanta; Sharma, A.L.The rapid depletion of fossil fuels and ever-growing energy demand have led to a search for renewable clean energy sources. The storage of renewable energy calls for immediate attention to the fabrication of efficient energy storage devices like supercapacitors (SCs). As an electrode material for SCs, MnO2 has gained wide research interest because of its high theoretical capacitance, variable oxidation state, vast abundance, and low cost. However, the low electric conductivity of MnO2 limits its practical application. The conductivity of MnO2 can be enhanced by tuning the electronic states through substitution doping with cobalt. In the present work, first principles analysis based on density functional theory (DFT) has been used to examine the quantum capacitance (CQC) and surface charge (Q) of Co-doped MnO2. Doping enhanced the structural stability, electrical conductivity, potential window, and quantum capacitance of ?-MnO2. The shortened band gap and localized states near the Fermi level improve the CQC of ?-MnO2. For the narrow potential range (?0.4 to 0.4 V), the CQC is observed to increase with doping concentration. The highest CQC value at +0.4 V is observed to be 2412.59 ?F cm?2 for Mn6Co2O16 (25% doping), five times higher than that of pristine MnO2 (471.18 ?F cm?2). Mn6Co2O16 also exhibits better CQC and �Q� at higher positive bias. Hence, it can be used as an anode material for asymmetric supercapacitors. All these results suggest better capacitive performance of Co-doped ?-MnO2 for aqueous SCs and as an anode material for asymmetric supercapacitors. � 2023 The Royal Society of Chemistry.Item All-redox hybrid supercapacitors based on carbon modified stacked zinc cobaltite nanosheets(Royal Society of Chemistry, 2023-09-12T00:00:00) Kour, Simran; Kour, Pawanpreet; Sharma, A.L.The role of energy in the present century has increased with the fast advancement of the global economy. In this regard, hybrid supercapacitors (HSCs) as energy storage systems have become an extensive research focus worldwide. This study reports the synthesis of carbon-loaded ZnCo2O4 stacked nanosheets via an in situ hydrothermal process followed by annealing. The electrochemical response was tested in a 2-electrode system. The optimized composite exhibited a capacitance of ?527.6 F g?1 at 5 mV s?1. The symmetric SC (SSC) possessed an energy density (Ed) of ?17.3 W h kg?1 corresponding to a power density (Pd) of 2.25 kW kg?1. Two asymmetric all-redox HSCs have also been fabricated using an optimized composite material as the positive electrode. The previously synthesized MnCo2O4/AC (HSC1) and MnO2/AC (HSC2) were taken as negative electrodes. HSC1 exhibited an Ed of ?24.4 W h kg?1 corresponding to a Pd of ?0.8 kW kg?1. On the other hand, HSC2 exhibited the highest Ed of ?30.8 W h kg?1 at 2.4 kW kg?1. The real-time application of the composite is tested with the fabricated HSCs. HSC1 exhibited a capacitive retention of ?72.2% after 10 000 cycles. On the other hand, HSC2 exhibited a capacitive retention of ?73.4% after 10 000 cycles. The SSC, HSC1, and HSC2 illuminated a 39 red LED panel for ?3 min, 7 min, and 13 min, respectively. The results suggested the promising performance of all-redox HSCs. The overall results present a sustainable approach for creating hierarchical energy materials for the construction of future energy-storage systems. � 2023 The Royal Society of Chemistry.Item Self-assembled carbon wrapped manganese cobaltite nano-composite with promising electrochemical performance for symmetric and asymmetric supercapacitor device(Elsevier Ltd, 2023-05-27T00:00:00) Kour, Simran; Kour, Pawanpreet; Sharma, A.L.The growing energy requirements of modern society have led to an intensive search for advanced supercapacitor (SC) electrode materials. Binary transition metal oxides with excellent supercapacitive performance are among the most promising materials. However, the phase transformation of these metal oxides during repeated charging/discharging is a major concern, which depletes their cyclic performance. Coating metal oxides with carbon can provide structural stability to the metal oxide, thereby increasing their cyclic life. In addition, the highly conductive carbon enhances the capacitance of metal oxides by allowing the effective transfer of charges from MnCo2O4 to the current collector. In this study, self-assembled carbon-wrapped MnCo2O4 composite has been prepared through a two-step process involving hydrothermal and solution-mixing processes. The structural/electrochemical performances of the composites have been investigated. The optimized composite offered a maximum capacitance of 626.8 Fg?1 withholding 98 % of capacitance for 6000 cycles. Furthermore, the electrochemical performance of the composite has also been tested in an all-redox symmetric SC (SSC) as well asymmetric (ASC) configuration. In the symmetric cell, 30.2 Whkg?1 of energy is reported for 1.6 kWkg?1 of power. The asymmetric cell with the optimized composite as a cathode and MnO2/Activated carbon as an anode was fabricated. The ASC displayed 45.5 Whkg?1 of energy corresponding to 10 kWkg?1. Three SSCs/ASCs in series illuminated a panel of 39 red-LEDs for 9 and 15 min, respectively. The results suggest the promising performance of such composites for hybrid supercapacitors. Thus, the fabrication of all-redox-type SSCs/ASCs can be a futuristic approach for hybrid storage systems. � 2023 Elsevier LtdItem MoS2-based core-shell nanostructures: Highly efficient materials for energy storage and conversion applications(Elsevier Ltd, 2023-04-19T00:00:00) Kour, Pawanpreet; Deeksha; Kour, Simran; Sharma, A.L.; Yadav, KamleshMolybdenum disulfide (MoS2) has acquired immense research recognition for various energy applications. The layered structure of MoS2 offers vast surface area and good exposure to active edge sites, thereby, making it a prominent candidate for lithium-ion batteries (LIBs), supercapacitors (SCs), and hydrogen evolution reactions (HERs). However, the limited conductivity, less number of active sites, and structural instability of MoS2 during continuous electrochemical cycling hinder its applications. In this regard, the formation of core-shell structures has been evolving as a prominent approach to uplift the electrochemical/electrocatalytic activity of MoS2 for energy-based applications. The unique core-shell composites of MoS2 with different electro-active materials exhibit superior electrochemical and electrocatalytic properties on account of the synergy of the core and the shell materials. These materials offer huge active area, high conductivity, an easy pathway for charge diffusion, and stable cyclic life leading to their outstanding electrochemical activity. In this review, various core-shell structures of MoS2 with carbon, metal oxides/sulfides, and conducting polymers are discussed for LIBs, SCs, and HERs. The function of core and shell materials in elevating the electrochemical activity of MoS2 based core-shell composites have been explored in detail. The effect of doping of core and shells on the performance of the composite has also been elucidated. The doped MoS2 based core-shell composites manifest tremendous electrochemical performance compared to the un-doped counterpart. Thus, these unique structured core-shell composites are regarded as futuristic candidates for energy storage and conversion systems. � 2023Item Mixed-phase MoS2 nanosheets anchored carbon nanofibers for high energy symmetric supercapacitors(Elsevier Ltd, 2023-03-14T00:00:00) Kour, Pawanpreet; Deeksha; Kour, Simran; Sharma, A.L.; Yadav, KamleshMixed-phase MoS2 (MS) nanosheets anchored carbon nanofibers (CNFs) have been synthesized via a hydrothermal route. The concentration of CNFs has been varied in the MS/CNF-x composite (where, x = 1, 1.5, 2, and 3 represents the molar concentration of CNFs) to investigate the impact of CNFs on the electrochemical behavior of the material. The incorporation of CNFs offers a conductive path for the diffusion of ions and provides structural support which limits the restacking of the MoS2 layers during the charging/discharging. The MS/CNF-2 composite delivered superior electrochemical performance compared with the other composites owing to the positive synergy between MoS2 and CNFs. The specific capacitance manifested by MS/CNF-2 (626.08 F g?1 at 1 A g?1) is about four times that of pristine MS (159.35 F g?1). It is also observed that MS/CNF-2 exhibited higher electrochemical stability than pristine MS. Furthermore, the symmetric supercapacitor (SSC) device achieved a tremendous energy density of 42.6 Wh kg?1 at 2.4 kW kg?1. To test its practical applicability, LEDs of different color (red, green, and blue) have been illuminated using a series combination of three symmetric electrode cells. The red, green, and blue LEDs lighted up for 15 mins, 7 mins, and 3 mins. The results demonstrate the superiority of the MS/CNF composite for symmetric supercapacitors. � 2023Item Hierarchical template-free chestnut-like manganese cobaltite for high-performance symmetric and asymmetric supercapacitor(Elsevier B.V., 2022-11-25T00:00:00) Kour, Simran; Tanwar, Shweta; Kour, Pawanpreet; Sharma, A.L.In this work, template-free Chestnut-like MnCo2O4 microspheres are synthesized using a straight-forward hydrothermal process succeeded by calcination. Urea as a reducing/precipitating agent can play an essential role in controlling the morphology of the material without using any additional surfactants or templates. The effect of reducing agent (Urea) on the structural and morphological evolution of MnCo2O4 has been studied. The electrochemical performance of the synthesized materials is investigated in a real device two-electrode cell configuration (symmetric and asymmetric system) rather than a three-electrode configuration. The two-electrode system gives more accurate and practical evaluation of the capacitive behavior of the material. The MnCo2O4 displayed the highest capacitance of 245.34 F g?1 at 5 mV s?1 for 0�1 V in a symmetric cell configuration. It also held an energy density of 22.24 Wh kg?1 at 1500 W kg?1. The optimized sample showed outstanding cyclic performance with only 3% of capacitance loss after 5000 cycles. Based on the structural and electrochemical findings, a charge storage mechanism has been proposed for the symmetric SC. Furthermore, a hybrid asymmetric supercapacitor with MnCo2O4 as a cathode and the previously synthesized MnO2/AC as an anode is also fabricated which exhibited an energy response of 30.12 Wh kg?1 for a power of 7000 W kg?1. For practical applications, different colored LEDs (red, yellow, green, and blue) and a panel with six red LEDs have been illuminated. The panel with six red LEDs is illuminated for 12 mins. for symmetric supercapacitor and 18 mins. for asymmetric supercapacitor. All these remarkable outcomes suggested that the synthesized material has wide potential for supercapacitors. � 2022Item Sustainable carbon coated ZrO2 electrodes with high capacitance retention for energy storage devices(Institute of Physics, 2022-08-09T00:00:00) Singh, Nirbhay; Tanwar, Shweta; Kour, Simran; Sharma, A.L.; Yadav, B.C.The rapid development of modern technology starves for future research to attain high-energy, high-power, and high cyclic stable energy-storage devices. Carbonaceous electrodes in supercapacitors provide a large-power device, which stores the charge between the surface of the carbonaceous electrode and the electrolyte layer. The commercially available electrode based on pure carbon suffers from low energy density. To overcome the mentioned issue, major efforts have been dedicated to enhancing the charge storage of carbonaceous electrodes by the addition of both pure capacitive material (such as Carbon and its derivative) and pure battery-type material (transition-metal oxide, hydroxides, etc). Mesoporous carbon due to its advanced feature along with ZrO2 good fit on performance and environmental aspect parameters. In this report, we have prepared environmentally friendly mesoporous carbon ZrO2 composite by the facile method, initially, ZrO2 is prepared hydrothermally after that mixing is done at room temperature to obtain the final product mesoporous carbon@ZrO2. The material structural, and microstructural examinations are done by x-ray diffraction analysis, and field emission scanning electron microscopy. The galvanostatic charging-discharging (GCD) analysis shows the specific capacitance of the device is 125 F g?1 and the energy density of the device is 25 Wh kg?1 at a current density of 0.5 A g?1. The GCD shows an extreme power density of 1201 W kg?1 at 1 mA. The cyclic voltammetry analysis shows the maximum specific capacitance of 54.5 F g?1 at 10 mV s?1. The long-term cyclic stability of up to 10 000 cycles is tested through GCD. The device shows high capacitance retention and Coulombic efficiency till the last GCD cycle at 82% and 100% respectively. The capacitive contribution is 55% for optimized electrodes. The prototype device formation and load light emitting diode (LED) testing are done at the laboratory. Based on experimental findings we have proposed a charge storage mechanism for a better understanding of readers. � 2022 IOP Publishing Ltd.Item A review on challenges to remedies of MnO2 based transition-metal oxide, hydroxide, and layered double hydroxide composites for supercapacitor applications(Elsevier Ltd, 2022-07-16T00:00:00) Kour, Simran; Tanwar, Shweta; Sharma, A.L.Supercapacitors are emerging energy storage devices admired in the research field due to their tremendous electrochemical properties parameters. Few peculiar properties parameters such as- high capacitance, large specific power/energy, excellent cyclic life, and rapid charging/discharging make them superior to other existing energy storage/conversion systems. Supercapacitors are predicted to be the potential energy resources for vast number of applications ranging from heavy electric vehicles to portable electrical/personal electronic appliances due to their ultra-fast charging behavior. The working efficiency of any supercapacitor is generally reliant on chosen materials acting as an electrode. In electrode materials series, manganese dioxide (MnO2) has been mostly explored and proven to be very effective and promising material as supercapacitor electrode. This is attributable to its superior theoretical capacitance, environmental friendliness, lower price, and vast profusion. But its deprived electrical conductivity and the volume expansion restrict its practical utility as a preferred electrode material. To make full utility of MnO2 materials, its composites with different type of materials have been tried and tested. The most fascinating composite electrode materials with MnO2 are discussed here in detail. The composites discussed in detail are MnO2/Transition metal oxides, MnO2/Transition metal hydroxides, and MnO2/Layered double hydroxides. A complete overview of these composites has been given and finally the recommendation of the best composites has been figured out systematically. The new opportunities for the future towards the advancement of MnO2 based composites are also being highlighted. � 2022 Elsevier LtdItem Study of electrochemical performance of 3-D MnO2 nanoflowers coated with carbon for supercapacitors(Elsevier Ltd, 2022-06-07T00:00:00) Kour, Simran; Tanwar, Shweta; Sharma, A.L.Manganese dioxide has gained wide research attention as a propitious material for supercapacitors attributable to its excellent characteristics like excellent theoretical capacitance, low-price, eco-friendly nature and profound abundance. Here in this paper, we have synthesized MnO2 nanoflowers via a hydrothermal route. The supercapacitive performance of MnO2 was tested. It exhibited a specific capacitance of 73.13 F g?1 at 10 mV s?1. To further boost the electrochemical performance of MnO2 nanoflowers, they have been coated with activated carbon via a very straight-forward sol-gel approach at room temperature. The obtained nano-composite (MnO2/AC) exhibited improved capacitance of 170.68 F g?1 at 10 mV s?1. The composite was able to attain an energy density of 20.89 Wh kg?1 (at 350 W kg?1). Thus, the composite material has broad potential applicability as supercapacitor electrode material. � 2022