Department Of Environmental Science And Technology

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Author: search.filters.author.Arora, MeenuHas files: Yes

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    In situ reductive regeneration of zerovalent iron nanoparticles immobilized on cellulose for atom efficient Cr( VI ) adsorption
    (Royal Society of Chemistry, 2015) Sharma,Archana Kumari; Kumar,Rabindra; Mittal, Sunil; Hussain,Shamima; Arora, Meenu; Sharma, R.C.; Babu, J. Nagendra
    Zerovalent iron nanoparticles (nZVI) (11.8 ± 0.2% w/w) immobilized on microcrystalline cellulose (C-nZVI) were synthesized and studied for Cr(VI) sorption. The material showed good atom economy for Cr(VI) adsorption (562.8 mg g−1 of nZVI). Oxidation of cellulose to cellulose dialdehyde leads to in situ regeneration of nZVI which is responsible for the atom efficient Cr(VI) sorption by C-nZVI.
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    1,3-Bis(cyanomethoxy)calix[4]arene capped CdSe quantum dots for the fluorogenic sensing of fluorene
    (Royal Society of Chemistry, 2017) Kumar, Rabindra; Arora, Meenu; Jain, A.K.; Babu, J. Nagendra
    Capping of 1,3-bis(cyanomethoxy)-tert-butylcalix[4]arene (CAD) onto CdSe quantum dots (QDs) was characterized by a fluorescence enhancement of the QDs (?em = 580 nm) upon surface interaction with the phenolic moiety of CAD. CAD@QD showed selective and sensitive 1.67 fold fluorescence enhancement in the presence of fluorene among fifteen PAHs. The fluorescence enhancement was characterized by monolayer adsorption of fluorene on to the surface of CAD@QD. The limit of detection for fluorene was observed to be 0.8 nM. This method was used and compared with detection of fluorene in spiked respirable dust (PM10) samples collected during an open biomass (stubble) burning event. ? The Royal Society of Chemistry.
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    Role of soil physicochemical characteristics on the present state of arsenic and its adsorption in alluvial soils of two agri-intensive region of Bathinda, Punjab, India
    (Springer Verlag, 2016) Kumar, Ravishankar; Kumar, Rabindra; Mittal, Sunil; Arora, Meenu; Babu, J. Nagendra
    Purpose: Arsenic (As) contamination of groundwater has received significant attention recently in district Bathinda, due to consequent health risk in this region. Soil is the one of the primary medium for arsenic transport to groundwater. Thus, there is an essential requirement for understanding the retention capacity and mobility of arsenic in the soils to ensure sustainability of the groundwater in the locality. Arsenic interaction with various physicochemical properties of soil would provide a better understanding of its leaching from the soil. Materials and methods: Fifty-one soil samples were collected from two regions of Bathinda district with extensive agricultural practices, namely, Talwandi Sabo and Goniana. The soils were analyzed for arsenic content and related physicochemical characteristic of the soil which influence arsenic mobility in soil. Adsorption studies were carried out to identify the arsenic mobilization characteristic of the soil. SEM-EDX and sequential extraction of arsenic adsorbed soil samples affirmed the arsenic adsorption and its mobility in soil, respectively. Multiple regression models have been formulated for meaningful soil models for the prediction of arsenic transport behavior and understand the adsorption and mobilization of arsenic in the soil matrices. Results and discussion: Region-wise analysis showed elevated levels of arsenic in the soil samples from Goniana region (mean 9.58?mg?kg?1) as compared to Talwandi Sabo block (mean 3.38?mg?kg?1). Selected soil samples were studied for As(V) and As(III) adsorption behavior. The characteristic arsenic adsorption by these soil samples fitted well with Langmuir, Freundlich, Temkin, and D-R isotherm with a qmax in the range of 45 to 254?mg?kg?1 and 116 to 250?mg?kg?1 for As(III) and As(V), respectively. Adsorption isotherms indicate weak arsenic retention capacity of the soil, which is attributed to the sandy loam textured soil and excessive fertilizer usage in this region. PCM and MLR analysis of the soil arsenic content and its adsorption strongly correlated with soil physicochemical parameters, namely, Mn, Fe, total/available phosphorus, and organic matter. Conclusions: Manganese and iron content were firmly established for retention of arsenic in soil, whereas its mobility was influenced by organic matter and total/available phosphorus. The poor adsorptive characteristic of these soils is the primary cause of higher arsenic concentration in groundwater of this region. A strong correlation between monitored arsenic and adsorbed As(III) with manganese suggests As(III) as the predominant species present in soil environment in this region. ? 2015, Springer-Verlag Berlin Heidelberg.