Department Of Environmental Science And Technology
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Item Removal of Congo red and Brilliant green dyes from aqueous solution using flower shaped ZnO nanoparticles(Elsevier Ltd, 2017) Kataria, N.; Garg, V.K.This work reports preparation and characterization of ZnO nanoparticles prepared by low temperature hydrothermal methods and their application for anionic dye (Congo red) and cationic dye (Brilliant green) removal from aqueous medium. The adsorption capacity of ZnO nanoparticles for Congo red dye and Brilliant green dye was up to 71.4 and 238 mg/g, respectively under selected process conditions. Dye adsorption behaviour has been explained applying different isotherms. Freundlich isotherm model best fitted to the dye removal data. Adsorption kinetics of both dyes is well explained by pseudo-second order model. Physical adsorption has been investigated using thermodynamic parameters viz., Gibb's free energy (?G?), enthalpy (?H?) and entropy (?S?). The reusability of ZnO nanoparticles was examined upto three cycles. ? 2017 Elsevier Ltd. All rights reserved.Item Preparation, characterization and potential use of flower shaped Zinc oxide nanoparticles (ZON) for the adsorption of Victoria Blue B dye from aqueous solution(Elsevier B.V., 2016) Kataria, N.; Garg, V.K.; Jain, M.; Kadirvelu, K.In present work, the performance and effectiveness of flower-shaped Zinc oxide nanoparticles (ZON) synthesised by hydrothermal method was evaluated for the adsorption of Victoria Blue B (VB B) dye from aqueous solution. ZON were characterised by using XRD, FTIR, SEM, EDX and DLS. Batch mode adsorption experiments were carried out to optimise the process conditions viz., pH, adsorbent dose, dye concentration, temperature, etc. The adsorption of cationic dye onto ZON surface was illustrated by Langmuir and Temkin isotherm models. The mechanism of dye adsorption onto the nanoparticles was explained by pseudo-second order kinetic model (R2???0.997). The thermodynamic parameters including Gibb's free energy (?G0), enthalpy (?H0), and entropy (?S0) were studied at different temperatures (10?70??C). The maximum adsorption capacity of VB B dye onto ZON was achieved up to 163?mg/g at pH 6.0 and temperature 27???1??C. ? 2016 The Society of Powder Technology Japan