Department Of Environmental Science And Technology
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Item Utilization of biosynthesized silica-supported iron oxide nanocomposites for the adsorptive removal of heavy metal ions from aqueous solutions(Springer Science and Business Media Deutschland GmbH, 2022-06-07T00:00:00) Garg, Rishav; Garg, Rajni; Khan, Md. Amir; Bansal, Manjeet; Garg, Vinod KumarThis study deals with heavy metal ions removal from simulated water using biosynthesized silica-supported iron oxide nanocomposites (nano-IOS). Agricultural and garden wastes have been utilized to prepare nano-IOS through a green synthesis process. Nano-IOS was characterized by XRD, SEM, FTIR, and zeta potential analysis. The nanocomposites were used to remove five heavy metals, viz., Pb2+, Cd2+, Ni2+, Cu2+, and Zn2+, with optimization of reaction parameters including pH, the concentration of heavy metals, adsorbent dosage, and contact time in batch mode experiments. The optimized dose of nano-IOS was 0.75�g/L for the adsorption of Pb2+, Cd2+, Ni2+, Cu2+, and Zn2+ (10.0�mg/L) with a contact duration of 70�min at pH 5.0 for Pb2+, Cd2+, and Cu2+ and 6.0 for Ni2+ and Zn2+. The adsorption behavior of the nano-adsorbent was well described by Langmuir adsorption isotherm and pseudo-second-order kinetic model indicating chemisorption on the surface of nano-IOS. The adsorption was also found spontaneous and endothermic. Thus, the environmentally benign and bio-synthesized nano-IOS can be utilized as an effective nano-adsorbent for the rapid sequestration of heavy metal ions�from water and wastewater. � 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.Item Sequestration of heavy metals from contaminated water using magnetic carbon nanocomposites(Elsevier B.V., 2022-03-30T00:00:00) Kataria, Navish; Chauhan, Amit Kumar; Garg, V.K.; Kumar, ParmodHeavy metals are toxic to flora, fauna and human beings. This study focused on removing toxic metals from an aqueous medium using magnetic carbon (Fe3O4@Carbon) nanocomposites. The biogenic green synthesis approach was used to fabricate the magnetic nanocomposite using low-cost poplar sawdust powder. The characterization of the nanocomposites was done using FESEM, TEM BET and FTIR. The sequestration of Pb (II), Cu (II) and Cr (VI) from water by Fe3O4@Carbon nanocomposites were studied under batch mode. The adsorption capacities for Pb (II), Cu (II) and Cr (VI) were 151.5, 48.08, and leaves49.29 mg/g respectively. The removal of metals by magnetic composites was studied in a mono, binary and tertiary network of metal ions. Adsorption isotherms studies indicated the chemosorption of Cu (II) and Cr (VI) onto the surface of nanocomposites. The thermodynamic analysis revealed that removal of studied metals ions is spontaneous and feasible. In this study, the effectiveness of magnetic nanocomposites is also explored for the removal of other heavy metals from tap water and simulated water sample. The heavy metal removal efficiency of the nanocomposites was not affected up to thrice reuse of adsorbent. � 2022Item A comprehensive physico-chemical quality and heavy metal health risk assessment study for phreatic water sources in Narora Atomic Power Station region, Narora, India(Springer Science and Business Media Deutschland GmbH, 2022-01-07T00:00:00) Singh, Manbir; Garg, V.K.An investigation of water quality and heavy metal distribution in the groundwater samples collected from the vicinity of Narora Atomic Power Station (NAPS), Narora, India, was conducted for the metals including Cu, Zn, Ni, Co, Cd, Pb, and Fe. A total of 16 water quality parameters were measured for all the groundwater samples, and TDS, TH, Mg2+, Ca2+, F?, and turbidity were found to be on the higher side in comparison to the prescribed limits of Indian standards. Geometrical mean concentrations for these heavy metals were found to be 0.049, 0.213, 0.23, 0.135, 0.017, 0.061, and BDL for Cu, Fe, Zn, Pb, Cd, Co, and Ni, respectively. Pb and Cd were more than the permissible limits (0.01�mg/L for Pb and 0.003 for Cd) prescribed for safe drinking water while Cu and Fe were exceeding the permissible limits of 0.05�mg/L and 0.3�mg/L in 32% and 36% samples, respectively. Health risk assessment was done by calculating total hazard quotient (THQ), and the values for all the metals were below the threshold value of 1.0 beyond which they may pose a significant risk. � 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.Item Sustainable remediation of heavy metals(Elsevier, 2021-04-30T00:00:00) Kumar, Hemant; Sahoo, Prafulla Kumar; Mittal, SunilHeavy metal contamination of soil and water bodies has been recognized as a potential threat to the entire biosphere, which accelerated after the industrial revolution and is presumed to be one of the major environmental challenges worldwide in the 21st century. The major health hazards associated with heavy metals include various types of cancers, organ damage, cardiovascular disease, nervous system disorders, etc. Several conventional techniques have been used for decades for the remediation of these noxious elements, but they have their own setbacks. The physical and chemical techniques are associated with high cost, intensive labor requirement, and ecologic destructive effect, which demand the search for alternative remediation techniques. Recently, biological remediation techniques, such as phytoremediation, bioremediation, biosorption, and microbial fuel cell-based techniques have come up as strong contenders and attracted more attention from researchers. Most of these techniques are considered as sustainable methods because of being cheaper, eco-friendly, and safer as compared with conventional methods. This chapter is an effort to provide an update on various remediation techniques and their advantages and disadvantages, with special focus on sustainable methods. This was carried out using the online database of Scopus, Web of Science, PupMed, Medline, ScienceDirect, Springer, Wiley Online Library, and Google Scholar, and all the available information from the past three decades were summarized and discussed. Also, effective sustainable technologies and their future prospects were highlighted. � 2021 Elsevier Inc.Item Hydrochemical characteristics and human health risk assessment of groundwater in the Shivalik region of Sutlej basin, Punjab, India(Springer Science and Business Media Deutschland GmbH, 2021-05-10T00:00:00) Mittal, Sunil; Sahoo, Prafulla Kumar; Sahoo, Sunil Kumar; Kumar, Ravishankar; Tiwari, Raghavendra PrasadShivalik region is one of the agri-intensive regions in Punjab, India, wherein groundwater quality is a major human health concern. In this study, a total of 57 groundwater samples were collected from the Rupnagar district of this region (one sample per 36 km2) to evaluate its quality, the role of hydrogeochemical processes in its contamination, and further their potential human health hazards. The results indicate that the major water chemistry is governed by carbonate weathering followed by silicate weathering. The Fe, Mg, Mn, Se, and HCO3- concentrations exceeded the BIS drinking water standards in 86, 51, 11, 9, and 79% of the samples, respectively. Piper and Durov plots indicated the dominance of Ca-HCO3- water types, followed by Ca-Mg-Cl- and Ca-Cl-. Furthermore, multivariate analyses indicated the geogenic origin for Fe, Mg, Mn, Se, SO42-, and anthropogenic sources (agrochemicals, cement factories, and fly ash) for NO3-, Cu, and Cr. The estimated carcinogenic risk of As and Cr falls under the very low (10-6) to low (10-5) risks category. Furthermore, the cumulative risk of non-carcinogenic contaminants (F-, U, NO3-) (HI-0.93) is at an alarming level and also close to the boundary line of USEPA limits (HI-1). There is an urgent need to undertake suitable policy measures for sustainability of groundwater quality. � 2021, Saudi Society for Geosciences.Item Management of banana crop waste biomass using vermicomposting technology(Elsevier Ltd, 2021-01-20T00:00:00) Mago, Monika; Yadav, Anoop; Gupta, Renuka; Garg, V.K.This study reports the vermicomposting of banana crop waste biomass by Eisenia fetida. Cow dung has been used as bulking agent in this study. The experiment was conducted in six vermireactors containing different ratios of banana leaf waste biomass (BL) and cow dung (CD) for 105 days. Earthworm activity significantly reduced pH, TOC, C:N and C:P ratio of the wastes. Whereas macronutrients and micronutrients content increased after vermicomposting. TOC content of wastes reduced by 40�64% and C:N ratio of the vermicomposts was in the range of 8.9�24.3. The benefit ratio for heavy metals (Cu, Fe, Zn, Cd, Pb, Mn and Cr) was in the range of 0.23�3.44. The results indicated that the growth and fecundity of the earthworms was best in the vermireactors having 20�40% BL. Finally, it was concluded that vermicomposting can be included in the overall scheme of banana crop waste management. � 2021 Elsevier LtdItem Quantification of groundwater-agricultural soil quality and associated health risks in the agri-intensive Sutlej River Basin of Punjab, India(Springer, 2020) Kumar, R; Mittal, S; Peechat, S; Sahoo, P.K; Sahoo, S.K.The quality of drinking water and agricultural soil significantly affects the health of residents of the area. The quality of groundwater used as drinking and irrigation water along with agricultural soil of an agri-intensive region of the Sutlej River Basin (SRB), Punjab (India), has been investigated in the present paper to further access their impacts on human health. The quality parameters studied are pH, conductivity, cations, anions and trace elements/heavy metals. The spatio-distribution maps of major contaminates have been made. The distribution of major existing groundwater and agricultural soil contaminants has also been illustrated using inverse distance weighting interpolation technique. Further, the Pearson correlation matrix and principal component analysis (PCA) have been applied to explore the correlation and source apportionment analysis for the contaminants. Finally, the health risk assessment study has also been performed. The results showed elevated levels [compared to BIS acceptable limits] of bicarbonate and total hardness in more than 90% groundwater samples, while the concentration of Se and U exceeded in around 25% samples. Spatial distribution maps showed a non-homologous distribution pattern for most of the heavy metals except Zn, indicating their different origins. The significant existence of Se and U in groundwater and low content in soils indicated their geogenic origin. The Gibbs diagram suggested that rock-water interaction is the primary process controlling the chemical evolution of the groundwater in the region. The PCA indicated that Cu, Mn, Pb, NO3? and SO42? in groundwater have an anthropogenic origin, whereas Fe, As and U are mainly of geogenic origin. Significant positive correlations of heavy metals with Fe and Al in soils indicated scavenging of these elements by Fe/Al-oxyhydroxides minerals. Based on SAR, Na%, PI and corrosivity ratio analysis, it can be concluded that groundwater of the region is suitable for irrigation purposes Further, health risk assessment study indicated Cr and As are the possible cancer risk posing elements from both soil and groundwater. Non-carcinogenic risk assessment showed that cumulative exposure (hazard index 1.98) of U (HQ 1.21), NO3? (HQ 0.37) and F? (HQ 0.34) might pose harmful impacts to residents through groundwater ingestion in the long term. Although currently the contaminants in the groundwater, soil system may not pose any human health risks, continuous long-term monitoring is required to keep a check on the changes in their quality with time. 2020, Springer Nature B.V.Item Pb2+ and Cd2+ recovery from water using residual tea waste and SiO2@TW nanocomposites(Elsevier, 2020) Joshi, S; Kataria, N; Garg, V.K; Kadirvelu, K.This work reports the fabrication of SiO2@TW nanocomposites and their application for Pb2+ and Cd2+ ions sequestration from simulated water. Residual tea waste has also been used for metal ions sequestration to compare the potential of SiO2@TW nanocomposites. The SEM, TEM, BET, FTIR and EDX techniques were employed for the characterization of SiO2@TW nanocomposites and residual tea waste. Particle sizes of SiO2@TW nanocomposites was in the range of 6.8-12 nm. The experiments were carried out in batch mode to explore the effect of various operating parameters on the sequestration of Pb2+ and Cd2+ ions from water. The experimental data was subjected to various thermodynamic, kinetic and isothermic models. According to Langmuir model, the maximum adsorption efficiency of the SiO2@TW nanocomposites was 153 mg/g for Pb2+ and 222 mg/g for Cd2+ but maximum adsorption efficiency of residual tea waste for Pb2+ was 125 mg/g and for Cd2+ was 142.9 mg/g. This study suggested that due to the presence of active sites SiO2@TW nanocomposites has greater potential for metal sequestration than residual tea waste. 2020 Elsevier LtdItem Optimization of Pb (II) and Cd (II) adsorption onto ZnO nanoflowers using central composite design: isotherms and kinetics modelling(Elsevier B.V., 2018) Kataria N.; Garg V.K.This study focused to optimization and screening of parameters for the adsorption of Cd (II) and Pb (II) onto ZnO nanoflowers. These were synthesized by low temperature hydrothermal methods. The surface properties of ZnO nanoflowers, before and after metal adsorption were characterized by FTIR, FESEM and EDX spectra. The adsorption parameters were optimized using central composites design. Adsorption behaviour and metals-adsorbent interaction was evaluated using batch mode experiments and isothermal models. Maximum adsorption capacity of ZnO nanoflowers was 71.5 mg/g and 115 mg/g for Cd (II) and Pb (II), respectively. In isotherms studies, Freundlich model is best fitted to metal adsorption data that indicated multilayer adsorption of Cd (II) and Pb (II) onto ZnO. The rate mechanism of metals ions adsorption was well explained by pseudo-second order models. The Adsorption efficiency of ZnO nanoflowers was analysed in spiked ground water sample also. The reusability of ZnO nanoflowers was also explored upto three cycles.Item Comparative analysis of vermicompost quality produced from rice straw and paper waste employing earthworm Eisenia fetida (Sav.)(Elsevier Ltd, 2018) Sharma, K.; Garg, V.K.Present study was undertaken to investigate the vermicomposting of two different organic wastes (rice straw and paper waste) employing, Eisenia fetida. Nine feedstocks were prepared with different ratios of wastes using cow dung as bulking substrate. After pre-composting, worms were allowed to feed on different feedstocks for 105 days under laboratory conditions. The results showed that NPK content was higher in the vermicompost. Heavy metal content was also higher in the vermicomposts. Whereas total organic carbon and C:N ratio were lower after vermicomposting, by 17.38?58.04% and 19?102% respectively. SEM images revealed changes in the morphology of vermicompost. Earthworm growth and reproduction was significant in different feedstocks except one containing 50% rice straw depicting that this ratio is not suitable for the earthworms. Results further demonstrated that proportion of bulking substrate affect the earthworm growth and reproduction. ? 2017 Elsevier Ltd