School Of Environment And Earth Sciences

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    Recent Advancement in Nanotechnology for the Treatment of Pharmaceutical Wastewater: Sources, Toxicity, and Remediation Technology
    (Springer Science and Business Media Deutschland GmbH, 2023-03-11T00:00:00) Kumar, Sandeep; Yadav, Sangita; Kataria, Navish; Chauhan, Amit Kumar; Joshi, Seema; Gupta, Renuka; Kumar, Parmod; Chong, Jun Wei Roy; Khoo, Kuan Shiong; Show, Pau Loke
    The textile, paper and pulp, distillery, and pharmaceutical industries are only a few of the many sectors that contribute significantly to the contamination of water bodies and their unsuitability for human use. Pharmaceuticals, which are credited with saving millions of lives in recent decades, have emerged as a new category of environmental hazard. Their prolonged presence in the environment has a number of negative effects, including gene toxicity, hormone interference, antibiotic resistance, the imposition of sex organs, and many others. To ensure that everyone in the world can access to uncontaminated and safe drinking water, it is important to treat pharmaceutical laden wastewater before discharge in fresh water body. Nanotechnology is getting significant attention due to enormous properties such as the high surface area to volume ratio, new optical properties, and desired shape. Nanomaterials might be a strong option for purifying water of a variety of environmental pollutants. This review also touches on several environmental aspects of pharmaceuticals, including (i) the current status of pharmaceuticals production and their use pattern, (ii) sources, occurrence, and transport behaviour of pharmaceuticals, (iii) analysis techniques and potential toxicity of pharmaceuticals and (iv) various conventional and advanced nanotechnology for water remediation. The present review is predominately designed to highlight the progress and major update in advantaged nanotechnology for remediation of pharmaceutical contaminated wastewater. The literature study (2015�2022) critically illustrated the recent pharmaceutical contaminations concerns and remediation efforts emphasizing nanotechnology like nanoadsorption, AOPs, nano-catalyst, electrochemical degradation and nanomembrane/nanofiltration technology. � 2023, The Author(s), under exclusive licence to Springer Nature Switzerland AG.
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    Amino-functionalized Magnetic Iron Nanoparticles As a Carrier for Laccase Enzyme and Its Potential to Degrade Chlorpyrifos in Contaminated Soil: Fate and Kinetics
    (Springer Science and Business Media Deutschland GmbH, 2022-04-14T00:00:00) Das, Anamika; Yogalakshmi, Kn
    The present study utilizes the covalent-crosslinking method to immobilize the�laccase enzyme on magnetic iron nanoparticles�and further assess its potential in degrading�chlorpyrifos in pesticide spiked�soil. The soil texture analysis revealed the presence of clay, silt and sand accounting to�7.1%, 14.3%, and 78.6%, respectively. The degradation of chlorpyrifos in spiked soil�using laccase enzyme�immobilized�magnetic iron nanoparticles was measured for 60�days�in a batch process. The results revealed a gradual increase in degradation efficiency showing around�29.3%, 43.8%, 56.3%, and 67.3% at the 20th, 30th, 40th, and 50th day�of incubation. A maximum degradation of�83.6% was observed on the 60th day of incubation. Intermediate products 2,4-bis(1,1 dimethylethyl) phenol, 1,2 benzenedicarboxylic acid, bis(2-methyl propyl) ester�and�piperidine confirmed the degradation of chlorpyrifos in soil. The piperidine originated in the chromatogram between�20�40�days of incubation and diminished later. Chlorpyrifos degradation followed pseudo first-order kinetics with a R2 of 0.96. Further, the nanoparticles showed no negative�impact on soil bacterial population during the antibacterial assay. The study confirms the degradation of chlorpyrifos in contaminated soil using laccase-immobilized nanoparticles. � 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.