School Of Basic And Applied Sciences

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    Structural, electrical properties and dielectric relaxations in Na+-ion-conducting solid polymer electrolyte
    (Institute of Physics Publishing, 2018) Arya, A.; Sharma, A.L.
    In this paper, we have studied the structural, microstructural, electrical, dielectric properties and ion dynamics of a sodium-ion-conducting solid polymer electrolyte film comprising PEO8-NaPF6+ x wt. % succinonitrile. The structural and surface morphology properties have been investigated, respectively using x-ray diffraction and field emission scanning electron microscopy. The complex formation was examined using Fourier transform infrared spectroscopy, and the fraction of free anions/ion pairs obtained via deconvolution. The complex dielectric permittivity and loss tangent has been analyzed across the whole frequency window, and enables us to estimate the DC conductivity, dielectric strength, double layer capacitance and relaxation time. The presence of relaxing dipoles was determined by the addition of succinonitrile (wt./wt.) and the peak shift towards high frequency indicates the decrease of relaxation time. Further, relations among various relaxation times () have been elucidated. The complex conductivity has been examined across the whole frequency window; it obeys the Universal Power Law, and displays strong dependency on succinonitrile content. The sigma representation () was introduced in order to explore the ion dynamics by highlighting the dispersion region in the Cole-Cole plot () in the lower frequency window; increase in the semicircle radius indicates a decrease of relaxation time. This observation is accompanied by enhancement in ionic conductivity and faster ion transport. A convincing, logical scheme to justify the experimental data has been proposed. ? 2018 IOP Publishing Ltd.
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    Facile chemical bath deposition method for interconnected nanofibrous polythiophene thin films and their use for highly efficient room temperature NO2 sensor application
    (Elsevier B.V., 2017) Kamble, D.B.; Sharma, A.K.; Yadav, J.B.; Patil, V.B.; Devan, R.S.; Jatratkar, A.A.; Yewale, M.A.; Ganbavle, V.V.; Pawar, S.D.
    Interconnected nanofibrous polythiophene (INPTh) film was deposited on the glass substrate through a simple chemical bath deposition method. The influence of monomer concentration on INPTh film properties as well as on NO2sensing properties of the film was studied. The morphological and structural studies were carried out using FTIR spectroscopy, FE-SEM microscope, and AFM analysis. The FTIR spectra confirmed the formation of PTH structure. The interconnected nanofibrous surface morphology was observed in FE-SEM images. The roughness of the film and thickness (225?nm?442?nm) was found to increase with monomer concentration up to 0.5?M, after that, both decreased at 0.6?M monomer concentration. The highest selectivity of PTh thin film towards NO2was observed than the other gases like H2S, SO2, NH3, CO and LPG. The influence of film morphology and thickness on gas sensing properties was observed, which was varied with monomer concentration. The film deposited at 0.5?M monomer concentration showed the highest NO2gas response of 47.58% at room temperature. Present results revealed that monomer concentration was also one of the deposition parameters for tuning the morphological as well as gas sensing properties of the chemical bath deposited PTh film. ? 2017 Elsevier B.V.
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    Amino acid functionalized zinc oxide nanostructures for cytotoxicity effect and hemolytic behavior: Theoretical and experimental studies
    (Elsevier Ltd, 2017) Singh, Satvinder; Singh, Baljinder; Sharma, Prateek; Mittal, Anu; Kumar, Sanjeev; Saini, G.S.S.; Tripathi, S.K.; Singh, Gurinder; Kaura, Aman
    Blending of theoretical and experimental approach, provide an important strategy in designing the nanostructure at a microscopic level and helps in predicting the response of synthesized material towards inhibition of the growth of breast cancer cell. In this work, ab initio calculations using super cell approach are performed for three different amino acids (AAs)-Histidine (His), Arginine (Arg) and Aspartic acid (Asp) coated Zinc oxide (ZnO) nanostructures to explain the growth mechanism of nanoparticles (NPs) of different shapes. Based on the first principles calculations, we reveal that ZnO-AA (Arg and Asp) NPs results in rod like and ZnO-His NPs lead to tablet like configuration. Similar morphologies are fabricated using AAs through synthetic route. The effect of concentration ratio of reactants and pH has been studied. As synthesized samples, are characterized by using Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Fourier Transform Infrared (FTIR) and UV?Vis spectroscopy techniques. Based on the results, a plausible mechanism of formation of nanostructures has been proposed. The nanostructures with rod like morphology are found to be biocompatible with normal red blood cells and show cytotoxic effect as evaluated from hemolysis and cytotoxicity assays on breast (MCF-7, T47D, MDA-MB-231) & prostate cancer (PC-3) cell lines. ? 2017 Elsevier Ltd
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    Melting, crystallization and storage stability of virgin coconut oil and its blends by differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR)
    (Springer India, 2017) Srivastava, Y.; Semwal, A.D.; Sajeevkumar, V.A.; Sharma, G.K.
    The blends were prepared of virgin coconut oil with refined soyabean oil (VCO-RSOY) and refined safflower oil (VCO-RSAFF). Blending with VCO improved the fatty acid composition which increased the shelf stability of 20:80 VCO-RSOY and VCO-RSAFF up to 12?months in different packaging systems such as low density polyethylene, linear low density polyethylene, metalized polyester pouches, polyethylene teteraphthalate, high density polyethylene (HDPE), Amber HDPE bottle. The specific spectral regions of FTIR proved to be very useful for the determination of adulteration as well as for the study of oxidation process. Band shifts observed at 3008, 1652, 1397, 1097, 912 and 845?cm?1 have been used to differentiate RSAFF from VCO. VCO spectrums did not have these chemical shifts. Further the spectrum of RSOY showed same band shifts as RSAFF except 1652, 1397, 869.6 and 845?cm?1. Differential Scanning Calorimetry provided useful information regarding the nature of thermodynamic changes related to physical state of vegetable oil. The physical state changes included melting and crystallization events which require the intake and release of energy. ? 2016, Association of Food Scientists & Technologists (India).
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    Correlation of microscopic interaction with electrical conductivity in polymer separator of energy storage devices
    (Springer Science and Business Media, LLC, 2017) Sharma, Parul Kumar; Sharma, Anshul Kumar; Sadiq, M.; Sharma, A. L.
    In the present report solid polymer nanocomposite (PNCs) comprising of (PEO)14+ NaClO4+ wt% BaTiO3has been prepared by solution casting method. Important characterization like: FTIR (Fourier Transform Infrared Spectroscopy), and conductivity have been performed for the applicability of the prepared materials in device application. The highest conductivity of the prepared polymer nanocomposite materials has been estimated 1?10?4Scm?1for 15 wt% of BaTiO3. A very fine correlation has been built among polymer-ion, ion-ion and polymer ion interaction with obtained conductivity results. ? Springer International Publishing Switzerland 2017.