Synthesis and photophysics of new unsymmetrically substituted 5,5?-diaryl-2,2?-bypiridine-based “push-pull” fluorophores

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Date

2019

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Elsevier Ltd

Abstract

New unsymmetrically substituted 5,5?-diaryl-2,2?-bypiridine “push-pull “ fluorophores were prepared in good yields via the “1,2,4-triazine method “/Suzuki coupling reaction sequence. The obtained fluorophores contain the “push-pull “ system with donor and acceptor moieties arranged in a D-?-A-?-D fashion, and that provides both the prospective photophysical properties and unique solvatocromic effects for the most representative compounds.

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Keywords

5,5?-diaryl-2,2?-bypiridine, Photophysical studies, Solvatochromism, Suzuki cross-coupling, “1,2,4-Triazine method “, “push-pull” fluorophores

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