Azaanthracenes via Inverse Electron-Demand Diels–Alder Reaction
| dc.contributor.author | Kopchuk, Dmitry S. | |
| dc.contributor.author | Chepchugov, N. V. | |
| dc.contributor.author | Taniya, Olga S. | |
| dc.contributor.author | Khasanov, A.F. | |
| dc.contributor.author | Giri,Kousik | |
| dc.contributor.author | Kovalev, Igor S. | |
| dc.contributor.author | Santra, S. | |
| dc.contributor.author | Zyryanov, Grigory V. | |
| dc.contributor.author | Majee, A. | |
| dc.contributor.author | Rusinov, V.L. | |
| dc.contributor.author | Chupakhin, O.N. | |
| dc.date.accessioned | 2018-01-31T07:31:02Z | |
| dc.date.accessioned | 2024-08-13T11:13:30Z | |
| dc.date.available | 2018-01-31T07:31:02Z | |
| dc.date.available | 2024-08-13T11:13:30Z | |
| dc.date.issued | 2016 | |
| dc.description.abstract | Significance: Azaanthracenes are important fluo- Comment: The benzyne derivative is generated in rophores that are used in a number of applications such as metal or pH sensors. In this report the authors describe a new synthesis of this type of structure via an inverse electron-demand aza- Diels–Alder reaction between a benzyne derivative and an electron-deficient triazine. situ from the diazotization of 2-amino-3-naphthoic acid. It was found that the cyano activating group at the 5-position of the triazine is crucial for the reaction to take place because it offers a smaller energy difference between the cycloaddition HOMO and LUMO. | en_US |
| dc.identifier.citation | Kopchuk, D.S., Chepchugov, N.V., Taniya, O.S. and et. al. Azaanthracenes via Inverse Electron-Demand Diels–Alder Reaction(2016) Tetrahedron Lett. 2016 , 57, 5639–5643. | en_US |
| dc.identifier.issn | 0040-4039 | |
| dc.identifier.uri | https://kr.cup.edu.in/handle/32116/552 | |
| dc.language.iso | en | en_US |
| dc.publisher | THIEME STUTTGART | en_US |
| dc.subject | aza-Diels–Alder reaction | en_US |
| dc.subject | triazines | en_US |
| dc.subject | fluorophores | en_US |
| dc.title | Azaanthracenes via Inverse Electron-Demand Diels–Alder Reaction | en_US |
| dc.type | Article | en_US |