All-redox hybrid supercapacitors based on carbon modified stacked zinc cobaltite nanosheets

dc.contributor.authorKour, Simran
dc.contributor.authorKour, Pawanpreet
dc.contributor.authorSharma, A.L.
dc.date.accessioned2024-01-21T10:42:57Z
dc.date.accessioned2024-08-13T12:45:02Z
dc.date.available2024-01-21T10:42:57Z
dc.date.available2024-08-13T12:45:02Z
dc.date.issued2023-09-12T00:00:00
dc.description.abstractThe role of energy in the present century has increased with the fast advancement of the global economy. In this regard, hybrid supercapacitors (HSCs) as energy storage systems have become an extensive research focus worldwide. This study reports the synthesis of carbon-loaded ZnCo2O4 stacked nanosheets via an in situ hydrothermal process followed by annealing. The electrochemical response was tested in a 2-electrode system. The optimized composite exhibited a capacitance of ?527.6 F g?1 at 5 mV s?1. The symmetric SC (SSC) possessed an energy density (Ed) of ?17.3 W h kg?1 corresponding to a power density (Pd) of 2.25 kW kg?1. Two asymmetric all-redox HSCs have also been fabricated using an optimized composite material as the positive electrode. The previously synthesized MnCo2O4/AC (HSC1) and MnO2/AC (HSC2) were taken as negative electrodes. HSC1 exhibited an Ed of ?24.4 W h kg?1 corresponding to a Pd of ?0.8 kW kg?1. On the other hand, HSC2 exhibited the highest Ed of ?30.8 W h kg?1 at 2.4 kW kg?1. The real-time application of the composite is tested with the fabricated HSCs. HSC1 exhibited a capacitive retention of ?72.2% after 10 000 cycles. On the other hand, HSC2 exhibited a capacitive retention of ?73.4% after 10 000 cycles. The SSC, HSC1, and HSC2 illuminated a 39 red LED panel for ?3 min, 7 min, and 13 min, respectively. The results suggested the promising performance of all-redox HSCs. The overall results present a sustainable approach for creating hierarchical energy materials for the construction of future energy-storage systems. � 2023 The Royal Society of Chemistry.en_US
dc.identifier.doi10.1039/d3se00680h
dc.identifier.issn23984902
dc.identifier.urihttps://kr.cup.edu.in/handle/32116/3780
dc.identifier.urlhttp://xlink.rsc.org/?DOI=D3SE00680H
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectCarbonen_US
dc.subjectCobalt compoundsen_US
dc.subjectElectrodesen_US
dc.subjectHierarchical systemsen_US
dc.subjectHydrothermal synthesisen_US
dc.subjectManganese oxideen_US
dc.subjectNanosheetsen_US
dc.subjectSupercapacitoren_US
dc.subjectZincen_US
dc.subjectZinc compoundsen_US
dc.subjectCarbon modifieden_US
dc.subjectEnergyen_US
dc.subjectEnergy densityen_US
dc.subjectGlobal economiesen_US
dc.subjectHybrid supercapacitorsen_US
dc.subjectMnO 2en_US
dc.subjectOptimized compositesen_US
dc.subjectPower densitiesen_US
dc.subjectStorage systemsen_US
dc.subjectSymmetricsen_US
dc.subjectEnergy storageen_US
dc.titleAll-redox hybrid supercapacitors based on carbon modified stacked zinc cobaltite nanosheetsen_US
dc.title.journalSustainable Energy and Fuelsen_US
dc.typeArticleen_US
dc.type.accesstypeClosed Accessen_US

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