Devan, R.S.Ma, Y.-R.More, M.A.Khare, R.T.Antad, V.V.Patil, R.A.Thakare, V.P.Dhayal, R.S.Schmidt-Mende, L.2018-07-142024-08-132018-07-142024-08-132016Devan, R. S., Ma, Y. R., More, M. A., Khare, R. T., Antad, V. V., Patil, R. A., . . . Schmidt-Mende, L. (2016). Promising field electron emission performance of vertically aligned one dimensional (1D) brookite (?) TiO<inf>2</inf>nanorods. Rsc Advances, 6(101), 98722-98729. doi: 10.1039/c6ra20747b2046206910.1039/c6ra20747bhttps://kr.cup.edu.in/handle/32116/1435We evidence field-electron emission (FE) studies on the large-area array of one-dimensional (1D) brookite (?) TiO2 nanorods. The pure 1D ?-TiO2 nanorods of 10 nm width and 760 nm long were synthesized on Si substrate utilizing hot-filament metal vapor deposition technique. X-ray diffraction (XRD) and transmission electron microscopy (TEM) analysis evidenced the ?-TiO2 nanorods to be composed of orthorhombic crystals in brookite (?) phase. X-ray photoemission spectroscopy (XPS) revealed the formation of pure stoichiometric (i.e. 1 : 1.98) 1D TiO2 nanorods. The values of turn-on field, required to draw current density of 10 ?A cm-2, was observed 3.9 V ?m-1 for pristine 1D ?-TiO2 nanorods emitters, which were found significantly lower than doped/undoped 1D TiO2 nanostructures (i.e. nanotubes, nanowires, nanorods) based field emitters. The enhanced FE behavior of the TiO2/Si emitter can be attributed to modulation of electronic properties due to the high aspect ratio of vertically aligned TiO2 nanorods. Furthermore, the orthodox emission situation of pristine TiO2/Si emitters exhibit good emission stability and reveal their potentials as promising FE material. ? 2016 The Royal Society of Chemistry.en-USAspect ratioElectron emissionElectronic propertiesField emissionHigh resolution transmission electron microscopyPhotoelectron spectroscopyTitanium dioxideTransmission electron microscopyX ray diffractionYarnEmission stabilityField electron emissionsHigh aspect ratioLarge area arraysOrthorhombic crystalsSi substratesVertically alignedX ray photoemission spectroscopyNanorodsArticlehttp://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C6RA20747B#!divAbstract