Kumar, AmitKumari, SapnaKumar, V.Kumar, PrashantThakur, Vikas N.Kumar, AshokGoyal, P.K.Arya, AnilSharma, A.L.2024-01-212024-08-132024-01-212024-08-132022-02-02957452210.1007/s10854-022-07798-6https://kr.cup.edu.in/handle/32116/3701In the present work, lead-free piezoelectric ceramics (Rx)(K0.5Na0.5)(Nb0.96Sb0.04O3)?x(Bi0.5Na0.5)(Zr0.8Sn0.1Hf0.1)O3 [abb. as (Rx)KNNS?xBNZSH, 0 ? x ? 0.04] were prepared via solid-state sintering technique. The thermal behavior of mixed powders has been investigated for x = 0, 0.02, and 0.04 using TGA-DSC analysis to estimate the calcination temperature. The structural, morphological, dielectric, ferroelectric and piezoelectric properties are analyzed through the appropriate characterization techniques. The X-ray diffraction (XRD) patterns demonstrate a pure perovskite phase structure for all the sintered samples. Further, the coexistence of rhombohedral to orthorhombic (R-O) phase is observed in ceramic sample with x = 0.02. The morphology of all the sintered samples exhibits an inhomogeneous, dense microstructure with the rectangular grain, while for x = 0.02, a relatively homogeneous distribution of grains is observed. BNZSH doping decreases the average grain size from 2.22 to 0.33�?m for x = 0 to x = 0.04, respectively. Owing to the presence of multiple-phase coexistence as well as the improved microstructure and enhanced dielectric properties (dielectric constant ?r = 1080, ?max = 5301; Curie temperature - TC ~ 317��C; dielectric loss - tan? ~ 6%) the ceramics with x = 0.02 has been found to have a large piezoelectric coefficient (d33) of ~180 pC/N, remnant polarization (Pr) ~ 16.7 �C/cm2 and coercive field (Ec) ~ 10.7�kV/cm. We believe it will expand the range of applications for KNN-based ceramics. � 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.en-USMorphologyPerovskitePhase structurePiezoelectric ceramicsPiezoelectricitySinteringCalcination temperatureDielectrics propertyLead free ceramicsLead-free piezoelectric ceramicMixed powderSintered samplesSolid state sinteringSynthesis phaseTga-dscThermal behavioursDielectric lossesArticlehttps://link.springer.com/10.1007/s10854-022-07798-6