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Recent synthetic strategies for monocyclic azole nucleus and its role in drug discovery and development
(Bentham Science Publishers B.V., 2018)
Background: In recent years, the development and diversification of heterocyclic compounds has become central to the discovery of bioactive compounds with novel or improved pharmacological properties. In particular, ...
Chitosan-supported copper as an efficient and recyclable heterogeneous catalyst for A3/decarboxylative A3-coupling reaction
(Elsevier Ltd, 2018)
Chitosan-supported copper (chit@copper) based heterogeneous catalysts have been explored for A3-coupling and decarboxylative A3-coupling. The developed protocol employs low catalyst loading, solventless condition and easy ...
Effects of lyotropic anions on thermodynamic stability and dynamics of horse cytochrome c
(Elsevier B.V., 2018)
This paper evaluates the effect of various lyotropic anions (chloride, sulfate, perchlorate, iodide, nitrate, bromide) on the thermodynamic stability and dynamics of native cytochrome c (Cyt c) at pH 7.0. The results of ...
Nickel oxide decorated zinc oxide composite nanorods: Excellent catalyst for photoreduction of hexavalent chromium
(Academic Press Inc., 2018)
In light of the growing interest and ability to search for new materials, we have synthesized Nickel oxide (NiO) nanoparticles decorated Zinc (ZnO) nanorods composite (NiO/ZnO) nanostructure. The NiO/ZnO heterostructure ...
Reductive-co-precipitated cellulose immobilized zerovalent iron nanoparticles in ionic liquid/water for Cr(VI) adsorption
(Springer Netherlands, 2018)
Microcrystalline cellulose immobilized zerovalent iron nanoparticles (CI-1-3) with different loading of 6, 12 and 24% w/w Fe0 were synthesized by NaBH4 reduction under simultaneous co-precipitation of cellulose from ionic ...
One-Pot Synthesis of Au Embedded ZnO Nanorods Composite Heterostructures with Excellent Photocatalytic Properties
(Wiley-Blackwell, 2018)
Here, we have designed a noble composite nanostructure by embedding gold (Au) nanoparticles into zinc oxide (ZnO) nanorods surface in one pot synthesis as a photocatalyst. The formation the composite nanostructure was ...
Synthesis, Structural Characterization, and H2 Evolution Study of a Spheroid-Shape Hydride-Rich Copper Nanocluster
(Wiley-Blackwell, 2018)
This study reports on new bis-2-butyl dithiophosphate-stabilized polyhydrido copper nanoclusters, [Cu32(H)20{S2P(O2Bu)2}12], 1H, and [Cu20H11{S2P(O2Bu)2}9], 2H. The clusters 1H and 2H have been characterized by a variety ...
Macromolecular crowding-induced molten globule states of the alkali pH-denatured proteins
(Elsevier B.V., 2018)
Structural and molecular properties extracted from circular dichroism (CD), tryptophan fluorescence and 1-anilino-8-napthalene sulfonate (ANS) binding experiments suggest that the high concentration of synthetic crowding ...
Factors defining the effects of macromolecular crowding on dynamics and thermodynamic stability of heme proteins in-vitro,
(Elsevier, 2018)
The role of crowding agents on structure and activities of heme proteins has been established. Analysis of kinetic and thermodynamic parameters measured for CO-dissociation reaction of natively-folded carbonmonoxycytochrome ...
Single-molecule force-unfolding of titin I27 reveals a correlation between the size of the surrounding anions and its mechanical stability
(Royal Societty of chemistry, 2018)
Each cellular protein is surrounded by a biochemical milieu that affects its stability and the associated function. The role of this surrounding milieu in the proteins’ mechanical stability remains largely unexplored. ...