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Polyhydrido Copper Clusters: Synthetic Advances, Structural Diversity, and Nanocluster-to-Nanoparticle Conversion
(American Chemical Society, 2016)
Conspectus: Metal hydride clusters have historically been studied to unravel their aesthetically pleasing molecular structures and interesting properties, especially toward hydrogen related applications. Central to this ...
Diselenophosphate-Induced Conversion of an Achiral [Cu20H11 {S2P (OiPr) 2} 9] into a Chiral [Cu20H11 {Se2P (OiPr) 2} 9] Polyhydrido Nanocluster.
(Wiley, 2015)
A polyhydrido copper nanocluster, [Cu20H11{Se2P(OiPr)2}9] (2H), which exhibits an intrinsically chiral inorganic core of C3 symmetry, was synthesized from achiral [Cu20H11{S2P(OiPr)2}9] (1H) of C3h symmetry by a ligand?exchange ...
Structural and electronic investigation of metal-semiconductor hybrid tetrapod hetero-structures
(Springer Verlag, 2017)
This article highlights the new electronic properties of tetrapod hetero-structures with metal Au core and semiconductor CdSe arms, which is one of the new classes of hybrid metal-semiconductor nanostructures. From the ...
Synthesis, Structural Characterization, and H2 Evolution Study of a Spheroid-Shape Hydride-Rich Copper Nanocluster
(Wiley-Blackwell, 2018)
This study reports on new bis-2-butyl dithiophosphate-stabilized polyhydrido copper nanoclusters, [Cu32(H)20{S2P(O2Bu)2}12], 1H, and [Cu20H11{S2P(O2Bu)2}9], 2H. The clusters 1H and 2H have been characterized by a variety ...
Macromolecular crowding-induced molten globule states of the alkali pH-denatured proteins
(Elsevier B.V., 2018)
Structural and molecular properties extracted from circular dichroism (CD), tryptophan fluorescence and 1-anilino-8-napthalene sulfonate (ANS) binding experiments suggest that the high concentration of synthetic crowding ...
Au/CdSe hybrid nanoflowers: a high photocurrent generating photoelectrochemical cells
(Springer, 2019)
Photoelectrochemical cell composed of solution-processed nanoflower heterostructure of Au core and eight CdSe petals was investigated for enhanced photocurrent generation. The electrode of CdSe nanorods displayed photocurrent ...
Zn(II) Di-isobutyldithiocarbamate Complex Enabled Efficient Synthesis of Au/ZnS Nanocomposite Core-shell in One Pot
(Wiley, 2019)
Here, we demonstrate a one pot synthesis of gold/zinc sulphide (Au/ZnS) core-shell type composite nanostructure via thermal decomposition of single molecular precursor Zn(II)di-isobutyldithiocarbamate complex. In these ...
Structural, kinetic and thermodynamic characterizations of SDS-induced molten globule state of a highly negatively charged cytochrome c
(Oxford University Press, 2019)
This study presents the structural, kinetic and thermodynamic characterizations of previously unknown submicellar concentrations of SDS-induced molten globule (MGSDS) state of a highly negatively charged basedenatured ...
Recent advances in the C(1)-functionalization of tetrahydroisoquinolines via multicomponent reactions
(Springer, 2020)
(Figure presented.) 1,2,3,4-Tetrahydroisoquinoline is an important structural motif of various natural products and therapeutic lead compounds. In recent years, considerable research interest has been witnessed toward ...
Imine/amide-imidazole conjugates derived from 5-amino-4-cyano-N1-substituted benzyl imidazole: Microwave-assisted synthesis and anticancer activity via selective topoisomerase-II-? inhibition
(Elsevier Ltd, 2015)
Microwave-accelerated synthesis and anticancer activity of novel imine/amide-imidazole conjugates derived from 5-amino-4-cyano-N1-substituted benzyl imidazole against a panel of seven cancer cell lines are reported for the ...